Photoluminescence, FTIR, and electrical characterization of samarium(III) chloride-doped polyaniline

Sadia Ameen; Vazid Ali; M. Zulfequar; M. Mazharul Haq; M. Husain

doi:10.1002/app.29613

Photoluminescence, FTIR, and electrical characterization of samarium(III) chloride-doped polyaniline

Sadia Ameen
, Vazid Ali
, M. Zulfequar
, M. Mazharul Haq
, M. Husain^*

^*Corresponding author for this work

Department of Bio-Convergence Science

Jamia Millia Islamia

Research output: Contribution to journal › Journal article › peer-review

13 Scopus citations

Abstract

The synthesized polyaniline (PANT) is doped with different concentrations of Samarium(III) chloride (SmCl₃). The electrical conductivity of doped PANT samples has been measured in the temperature range (300-400K). It has been found that dc conductivity increases with the increase of dopant concentration. Different parameters, based on the conductivity, such as pre-ex-ponential factor (θ₀) and activation energy (δE) have also been calculated. These parameters exhibit information about the nature and suitability of the dopant. Doped samples are characterized by FTIR and photoluminescence studies, which show the interaction of dopant with PANI. Two sharp peaks of different intensities from PL spectra at 388 and 604nm have appeared in doped PANI, which might be due to the effect of SmCl₃. It has been observed that SmCl₃ (dopant) shows noticeable changes in the electrical and spectroscopic properties of doped PANI.

Original language	English
Pages (from-to)	2315-2319
Number of pages	5
Journal	Journal of Applied Polymer Science
Volume	112
Issue number	4
DOIs	https://doi.org/10.1002/app.29613
State	Published - 2009.05.15

Keywords

Conducting polymers
Doping
FTIR
Photoluminescence

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10.1002/app.29613

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@article{7459e6633f7448c888c91f4c048c9fdc,

title = "Photoluminescence, FTIR, and electrical characterization of samarium(III) chloride-doped polyaniline",

abstract = "The synthesized polyaniline (PANT) is doped with different concentrations of Samarium(III) chloride (SmCl3). The electrical conductivity of doped PANT samples has been measured in the temperature range (300-400K). It has been found that dc conductivity increases with the increase of dopant concentration. Different parameters, based on the conductivity, such as pre-ex-ponential factor (θ0) and activation energy (δE) have also been calculated. These parameters exhibit information about the nature and suitability of the dopant. Doped samples are characterized by FTIR and photoluminescence studies, which show the interaction of dopant with PANI. Two sharp peaks of different intensities from PL spectra at 388 and 604nm have appeared in doped PANI, which might be due to the effect of SmCl3. It has been observed that SmCl3 (dopant) shows noticeable changes in the electrical and spectroscopic properties of doped PANI.",

keywords = "Conducting polymers, Doping, FTIR, Photoluminescence",

author = "Sadia Ameen and Vazid Ali and M. Zulfequar and Haq, \{M. Mazharul\} and M. Husain",

year = "2009",

month = may,

day = "15",

doi = "10.1002/app.29613",

language = "English",

volume = "112",

pages = "2315--2319",

journal = "Journal of Applied Polymer Science",

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}

TY - JOUR

T1 - Photoluminescence, FTIR, and electrical characterization of samarium(III) chloride-doped polyaniline

AU - Ameen, Sadia

AU - Ali, Vazid

AU - Zulfequar, M.

AU - Haq, M. Mazharul

AU - Husain, M.

PY - 2009/5/15

Y1 - 2009/5/15

N2 - The synthesized polyaniline (PANT) is doped with different concentrations of Samarium(III) chloride (SmCl3). The electrical conductivity of doped PANT samples has been measured in the temperature range (300-400K). It has been found that dc conductivity increases with the increase of dopant concentration. Different parameters, based on the conductivity, such as pre-ex-ponential factor (θ0) and activation energy (δE) have also been calculated. These parameters exhibit information about the nature and suitability of the dopant. Doped samples are characterized by FTIR and photoluminescence studies, which show the interaction of dopant with PANI. Two sharp peaks of different intensities from PL spectra at 388 and 604nm have appeared in doped PANI, which might be due to the effect of SmCl3. It has been observed that SmCl3 (dopant) shows noticeable changes in the electrical and spectroscopic properties of doped PANI.

AB - The synthesized polyaniline (PANT) is doped with different concentrations of Samarium(III) chloride (SmCl3). The electrical conductivity of doped PANT samples has been measured in the temperature range (300-400K). It has been found that dc conductivity increases with the increase of dopant concentration. Different parameters, based on the conductivity, such as pre-ex-ponential factor (θ0) and activation energy (δE) have also been calculated. These parameters exhibit information about the nature and suitability of the dopant. Doped samples are characterized by FTIR and photoluminescence studies, which show the interaction of dopant with PANI. Two sharp peaks of different intensities from PL spectra at 388 and 604nm have appeared in doped PANI, which might be due to the effect of SmCl3. It has been observed that SmCl3 (dopant) shows noticeable changes in the electrical and spectroscopic properties of doped PANI.

KW - Conducting polymers

KW - Doping

KW - FTIR

KW - Photoluminescence

UR - https://www.scopus.com/pages/publications/64249151134

U2 - 10.1002/app.29613

DO - 10.1002/app.29613

M3 - Journal article

AN - SCOPUS:64249151134

SN - 0021-8995

VL - 112

SP - 2315

EP - 2319

JO - Journal of Applied Polymer Science

JF - Journal of Applied Polymer Science

IS - 4

ER -

Photoluminescence, FTIR, and electrical characterization of samarium(III) chloride-doped polyaniline

Abstract

Keywords

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