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Poly(Vinylidene fluoride-co-hexa fluoropropylene)/Poly vinyl alcohol porous membranes for the application of fuel cells

  • G. Gnana Kumar
  • , Dae Nyung Lee
  • , Pil Kim
  • , Kee Suk Nahm
  • , R. Nimmaelizabeth
  • Jeonbuk National University
  • Madurai Kamaraj University

Research output: Contribution to journalJournal articlepeer-review

Abstract

Composite polymer electrolyte membranes PVdF-HFP/PVA were prepared by phase inversion technique. The prepared membranes were soaked in DI water and 6 M sulfuric acid in order to attain the porosity and functionality. The extended porosity was determined by scanning electron microscopy (SEM). Amorphous phase was enhanced by the inclusion of acid. Amorphous state provides a free path which causes the movement of ions leading to an increase in the conductivity. The infra-red spectroscopic measurements revealed the presence of acid moieties in the composite membranes and confirmed its functionality. Thermal gravimetric analysis showed high thermal stability of the membrane. The polymer membrane prepared with extended porosity [PVdF-HFP (7 wt.%)/PVA (4.6 wt.%)] exhibited maximum protonic conductivity due to the effect of high porous nature and the entrapment of acid moieties.

Original languageEnglish
Pages (from-to)55-61
Number of pages7
JournalJournal of Polymer Research
Volume16
Issue number1
DOIs
StatePublished - 2009.01

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

  1. SDG 7 - Affordable and Clean Energy
    SDG 7 Affordable and Clean Energy

Keywords

  • Amorphous
  • Conductivity
  • Membrane
  • Polymer
  • Porosity

Quacquarelli Symonds(QS) Subject Topics

  • Materials Science
  • Engineering - Petroleum
  • Chemistry

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