Preparation of primary-amine functionalized poly(2,5-benzimidazole) membrane for fuel cells

Nguyen Thi Xuan Hien; Nam Hoon Kim; Hong Ki Lee; Joong Hee Lee

doi:10.4028/www.scientific.net/AMR.123-125.1095

Preparation of primary-amine functionalized poly(2,5-benzimidazole) membrane for fuel cells

Nguyen Thi Xuan Hien
, Nam Hoon Kim
, Hong Ki Lee
, Joong Hee Lee

Department of Nano Convergence Engineering

Jeonbuk National University
Woosuk University

Research output: Contribution to conference › Conference paper › peer-review

1 Scopus citations

Abstract

Acid doped polybenzimidazole membrane has been prepared for proton exchange membrane fuel cell. The present work aims at improving the proton conductivity without losing mechanical properties at high doping level by modifying poly (2,5-benzimidazole) (ABPBI). The nitration of ABPBI has been carried out with acid mixture of HNO₃ and H₂SO₄ at 30°C. This nitro compound has been reduced successfully by stannous chloride/dimethylacetamide in presence of hydrochloric acid. Fourier transform infrared (FT-IR) spectra confirm the presence of primary amine groups in the ABPBI structure. The primary amine functionalized ABPBI has been cross-linked by hexamethylene diisocyanate and casted onto glass Petridis using dimethyl sulfoxide as solvent. Membrane doped with phosphoric acid shows comparatively higher proton conductivity, but lower tensile strength.

Original language	English
Title of host publication	Multi-Functional Materials and Structures III
Pages	1095-1098
Number of pages	4
DOIs	https://doi.org/10.4028/www.scientific.net/AMR.123-125.1095
State	Published - 2010
Event	3rd International Conference on Multi-Functional Materials and Structures, MFMS 2010 - Jeonju, Korea, Republic of Duration: 2010.09.14 → 2010.09.18

Publication series

Name	Advanced Materials Research
Volume	123-125
ISSN (Print)	1022-6680

Conference

Conference	3rd International Conference on Multi-Functional Materials and Structures, MFMS 2010
Country/Territory	Korea, Republic of
City	Jeonju
Period	10.09.14 → 10.09.18

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Conducting polymers
Fuel cells
Polybenzimidazole
Polymeric materials

Quacquarelli Symonds(QS) Subject Topics

Engineering & Technology

Access to Document

10.4028/www.scientific.net/AMR.123-125.1095

Cite this

@inproceedings{c9094ff73a034e80a39925a59a1130db,

title = "Preparation of primary-amine functionalized poly(2,5-benzimidazole) membrane for fuel cells",

abstract = "Acid doped polybenzimidazole membrane has been prepared for proton exchange membrane fuel cell. The present work aims at improving the proton conductivity without losing mechanical properties at high doping level by modifying poly (2,5-benzimidazole) (ABPBI). The nitration of ABPBI has been carried out with acid mixture of HNO3 and H2SO4 at 30°C. This nitro compound has been reduced successfully by stannous chloride/dimethylacetamide in presence of hydrochloric acid. Fourier transform infrared (FT-IR) spectra confirm the presence of primary amine groups in the ABPBI structure. The primary amine functionalized ABPBI has been cross-linked by hexamethylene diisocyanate and casted onto glass Petridis using dimethyl sulfoxide as solvent. Membrane doped with phosphoric acid shows comparatively higher proton conductivity, but lower tensile strength.",

keywords = "Conducting polymers, Fuel cells, Polybenzimidazole, Polymeric materials",

author = "Hien, \{Nguyen Thi Xuan\} and Kim, \{Nam Hoon\} and Lee, \{Hong Ki\} and Lee, \{Joong Hee\}",

year = "2010",

doi = "10.4028/www.scientific.net/AMR.123-125.1095",

language = "English",

isbn = "9780878492466",

series = "Advanced Materials Research",

pages = "1095--1098",

booktitle = "Multi-Functional Materials and Structures III",

note = "3rd International Conference on Multi-Functional Materials and Structures, MFMS 2010 ; Conference date: 14-09-2010 Through 18-09-2010",

}

Hien, NTX, Kim, NH, Lee, HK & Lee, JH 2010, Preparation of primary-amine functionalized poly(2,5-benzimidazole) membrane for fuel cells. in Multi-Functional Materials and Structures III. Advanced Materials Research, vol. 123-125, pp. 1095-1098, 3rd International Conference on Multi-Functional Materials and Structures, MFMS 2010, Jeonju, Korea, Republic of, 10.09.14. https://doi.org/10.4028/www.scientific.net/AMR.123-125.1095

TY - GEN

T1 - Preparation of primary-amine functionalized poly(2,5-benzimidazole) membrane for fuel cells

AU - Hien, Nguyen Thi Xuan

AU - Kim, Nam Hoon

AU - Lee, Hong Ki

AU - Lee, Joong Hee

PY - 2010

Y1 - 2010

N2 - Acid doped polybenzimidazole membrane has been prepared for proton exchange membrane fuel cell. The present work aims at improving the proton conductivity without losing mechanical properties at high doping level by modifying poly (2,5-benzimidazole) (ABPBI). The nitration of ABPBI has been carried out with acid mixture of HNO3 and H2SO4 at 30°C. This nitro compound has been reduced successfully by stannous chloride/dimethylacetamide in presence of hydrochloric acid. Fourier transform infrared (FT-IR) spectra confirm the presence of primary amine groups in the ABPBI structure. The primary amine functionalized ABPBI has been cross-linked by hexamethylene diisocyanate and casted onto glass Petridis using dimethyl sulfoxide as solvent. Membrane doped with phosphoric acid shows comparatively higher proton conductivity, but lower tensile strength.

AB - Acid doped polybenzimidazole membrane has been prepared for proton exchange membrane fuel cell. The present work aims at improving the proton conductivity without losing mechanical properties at high doping level by modifying poly (2,5-benzimidazole) (ABPBI). The nitration of ABPBI has been carried out with acid mixture of HNO3 and H2SO4 at 30°C. This nitro compound has been reduced successfully by stannous chloride/dimethylacetamide in presence of hydrochloric acid. Fourier transform infrared (FT-IR) spectra confirm the presence of primary amine groups in the ABPBI structure. The primary amine functionalized ABPBI has been cross-linked by hexamethylene diisocyanate and casted onto glass Petridis using dimethyl sulfoxide as solvent. Membrane doped with phosphoric acid shows comparatively higher proton conductivity, but lower tensile strength.

KW - Conducting polymers

KW - Fuel cells

KW - Polybenzimidazole

KW - Polymeric materials

UR - https://www.scopus.com/pages/publications/78650722839

U2 - 10.4028/www.scientific.net/AMR.123-125.1095

DO - 10.4028/www.scientific.net/AMR.123-125.1095

M3 - Conference paper

AN - SCOPUS:78650722839

SN - 9780878492466

T3 - Advanced Materials Research

SP - 1095

EP - 1098

BT - Multi-Functional Materials and Structures III

T2 - 3rd International Conference on Multi-Functional Materials and Structures, MFMS 2010

Y2 - 14 September 2010 through 18 September 2010

ER -

Preparation of primary-amine functionalized poly(2,5-benzimidazole) membrane for fuel cells

Abstract

Publication series

Conference

UN SDGs

Keywords

Quacquarelli Symonds(QS) Subject Topics

Access to Document

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