Properties of N,N-bis[2-(isonicotinoyloxy)ethyl]-p-toluenesulfonamide. Structures of its silver(I) complexes via anion effects

Hwan Noh Tae; Jung Choi Youn; Jo Ha Byung; Sung Jin Jong; Ok Sang Jung

doi:10.5012/bkcs.2008.29.11.2157

Properties of N,N-bis[2-(isonicotinoyloxy)ethyl]-p-toluenesulfonamide. Structures of its silver(I) complexes via anion effects

Hwan Noh Tae
, Jung Choi Youn
, Jo Ha Byung
, Sung Jin Jong
, Ok Sang Jung

Chemistry Education

Pusan National University
Eulji University
Korea Basic Science Institute

Research output: Contribution to journal › Journal article › peer-review

Abstract

N,N-Bis[2-(isonicotinoyloxy)ethyl]-p-toluenesulfonamide (L) as a new ligand was synthesized and characterized. The photoluminescence spectrum of L shows a bright blue emission at 417 nm. The slow diffusion of an organic solution of L into an aqueous solution of AgX (X = BF₄^- and ClO ₄) affords a metallacyclodimer consisting of [Ag(L)] ₂X₂. Each L acts as a bidentate fashion, and thus connects two Ag(I) ions to form the metallacyclodimer. For [Ag(L)]₂(BF ₄)₂, the BF₄^- anions are positioned around Ag(I) ion, and for [Ag(L)]₂-(ClO₄)₂, the ClO₄ anions are positioned at the metallacyclodimeric ring. The delicate difference between both structures in solid state can be explained by the coordinating ability of anions.

Original language	English
Pages (from-to)	2157-2160
Number of pages	4
Journal	Bulletin of the Korean Chemical Society
Volume	29
Issue number	11
DOIs	https://doi.org/10.5012/bkcs.2008.29.11.2157
State	Published - 2008.11.20

Keywords

Anion effects
Crystal structures
Metallacyclodimers
N,N-bis[2-(isonicotinoyloxy)ethyl]-p-toluenesulfonamide
Silver(I) complexes

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10.5012/bkcs.2008.29.11.2157

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@article{c130924b24e4461fa129d29db0ffc440,

title = "Properties of N,N-bis[2-(isonicotinoyloxy)ethyl]-p-toluenesulfonamide. Structures of its silver(I) complexes via anion effects",

abstract = "N,N-Bis[2-(isonicotinoyloxy)ethyl]-p-toluenesulfonamide (L) as a new ligand was synthesized and characterized. The photoluminescence spectrum of L shows a bright blue emission at 417 nm. The slow diffusion of an organic solution of L into an aqueous solution of AgX (X = BF4- and ClO 4) affords a metallacyclodimer consisting of [Ag(L)] 2X2. Each L acts as a bidentate fashion, and thus connects two Ag(I) ions to form the metallacyclodimer. For [Ag(L)]2(BF 4)2, the BF4- anions are positioned around Ag(I) ion, and for [Ag(L)]2-(ClO4)2, the ClO4 anions are positioned at the metallacyclodimeric ring. The delicate difference between both structures in solid state can be explained by the coordinating ability of anions.",

keywords = "Anion effects, Crystal structures, Metallacyclodimers, N,N-bis[2-(isonicotinoyloxy)ethyl]-p-toluenesulfonamide, Silver(I) complexes",

author = "Tae, \{Hwan Noh\} and Youn, \{Jung Choi\} and Byung, \{Jo Ha\} and Jong, \{Sung Jin\} and Jung, \{Ok Sang\}",

year = "2008",

month = nov,

day = "20",

doi = "10.5012/bkcs.2008.29.11.2157",

language = "English",

volume = "29",

pages = "2157--2160",

journal = "Bulletin of the Korean Chemical Society",

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TY - JOUR

T1 - Properties of N,N-bis[2-(isonicotinoyloxy)ethyl]-p-toluenesulfonamide. Structures of its silver(I) complexes via anion effects

AU - Tae, Hwan Noh

AU - Youn, Jung Choi

AU - Byung, Jo Ha

AU - Jong, Sung Jin

AU - Jung, Ok Sang

PY - 2008/11/20

Y1 - 2008/11/20

N2 - N,N-Bis[2-(isonicotinoyloxy)ethyl]-p-toluenesulfonamide (L) as a new ligand was synthesized and characterized. The photoluminescence spectrum of L shows a bright blue emission at 417 nm. The slow diffusion of an organic solution of L into an aqueous solution of AgX (X = BF4- and ClO 4) affords a metallacyclodimer consisting of [Ag(L)] 2X2. Each L acts as a bidentate fashion, and thus connects two Ag(I) ions to form the metallacyclodimer. For [Ag(L)]2(BF 4)2, the BF4- anions are positioned around Ag(I) ion, and for [Ag(L)]2-(ClO4)2, the ClO4 anions are positioned at the metallacyclodimeric ring. The delicate difference between both structures in solid state can be explained by the coordinating ability of anions.

AB - N,N-Bis[2-(isonicotinoyloxy)ethyl]-p-toluenesulfonamide (L) as a new ligand was synthesized and characterized. The photoluminescence spectrum of L shows a bright blue emission at 417 nm. The slow diffusion of an organic solution of L into an aqueous solution of AgX (X = BF4- and ClO 4) affords a metallacyclodimer consisting of [Ag(L)] 2X2. Each L acts as a bidentate fashion, and thus connects two Ag(I) ions to form the metallacyclodimer. For [Ag(L)]2(BF 4)2, the BF4- anions are positioned around Ag(I) ion, and for [Ag(L)]2-(ClO4)2, the ClO4 anions are positioned at the metallacyclodimeric ring. The delicate difference between both structures in solid state can be explained by the coordinating ability of anions.

KW - Anion effects

KW - Crystal structures

KW - Metallacyclodimers

KW - N,N-bis[2-(isonicotinoyloxy)ethyl]-p-toluenesulfonamide

KW - Silver(I) complexes

UR - https://www.scopus.com/pages/publications/57349126480

U2 - 10.5012/bkcs.2008.29.11.2157

DO - 10.5012/bkcs.2008.29.11.2157

M3 - Journal article

AN - SCOPUS:57349126480

SN - 0253-2964

VL - 29

SP - 2157

EP - 2160

JO - Bulletin of the Korean Chemical Society

JF - Bulletin of the Korean Chemical Society

IS - 11

ER -

Properties of N,N-bis[2-(isonicotinoyloxy)ethyl]-p-toluenesulfonamide. Structures of its silver(I) complexes via anion effects

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Keywords

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