Relationship between the ratio of ligand to metal and the coordinating ability of anions. Synthesis and structural properties of AgX-bearing bis(4-pyridyl)dimethylsilane (X - = NO 2 -, NO 3 -, CF 3so 3 -, and PF 6 -)

Jung Woon Lee; Eun Ae Kim; Yun Du Kim; Young A. Lee; Youngshang Pak; Ok Sang Jung

doi:10.1021/ic048537r

Relationship between the ratio of ligand to metal and the coordinating ability of anions. Synthesis and structural properties of AgX-bearing bis(4-pyridyl)dimethylsilane (X ^- = NO ₂ ^-, NO ₃ ^-, CF ₃so ₃ ^-, and PF ₆ ^-)

Jung Woon Lee
, Eun Ae Kim
, Yun Du Kim
, Young A. Lee
, Youngshang Pak
, Ok Sang Jung^*

^*Corresponding author for this work

Department of Chemistry

Pusan National University

Research output: Contribution to journal › Journal article › peer-review

94 Scopus citations

Abstract

Studies of the anion effects on the molecular construction of a series of AgX complexes with bis(4-pyridyl)-dimethylsilane (L) (X ^- = NO ₂ ^-, NO ₃ ^-, CF ₃SO ₃, and PF ₆ ^-) have been carried out. Formation of the skeletal bonds appears to be primarily associated with a suitable combination of bidentate N-donors of L and a variety of coordination geometries of Ag(I) ions. The L:Ag(I) ratios of the products are dependent on the nature of the polyatomic anions. The 1:1 adduct Ag(I)-L for NO ₂ ^-, 3:4 adduct for NO ₃ ^-, 2:3 adduct for CF ₃SO ₃ ^-, and 1:2 adduct for PF ₆ ^- have been obtained. A linear relationship between the ratio of ligand to metal and the coordinating ability of anions was observed. [Ag(NO ₂)(L)] has a unique sheet structure consisting of double helices, and [Ag ₃(L) ₄](NO ₃) ₃ is a 2 nm thick interwoven sheet structure consisting of nanotubes. The compound [Ag ₂(L) ₃](CF ₃SO ₃) ₂ affords a characteristic ladder-type channel structure, and [Ag(L) ₂](PF ₆) is a simple 2D grid structure.

Original language	English
Pages (from-to)	3151-3155
Number of pages	5
Journal	Inorganic Chemistry
Volume	44
Issue number	9
DOIs	https://doi.org/10.1021/ic048537r
State	Published - 2005.05.2

Quacquarelli Symonds(QS) Subject Topics

Engineering - Petroleum
Chemistry

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@article{c91308cc7259490c937ce80ccc26172e,

title = "Relationship between the ratio of ligand to metal and the coordinating ability of anions. Synthesis and structural properties of AgX-bearing bis(4-pyridyl)dimethylsilane (X - = NO 2 -, NO 3 -, CF 3so 3 -, and PF 6 -)",

abstract = "Studies of the anion effects on the molecular construction of a series of AgX complexes with bis(4-pyridyl)-dimethylsilane (L) (X - = NO 2 -, NO 3 -, CF 3SO 3, and PF 6 -) have been carried out. Formation of the skeletal bonds appears to be primarily associated with a suitable combination of bidentate N-donors of L and a variety of coordination geometries of Ag(I) ions. The L:Ag(I) ratios of the products are dependent on the nature of the polyatomic anions. The 1:1 adduct Ag(I)-L for NO 2 -, 3:4 adduct for NO 3 -, 2:3 adduct for CF 3SO 3 -, and 1:2 adduct for PF 6 - have been obtained. A linear relationship between the ratio of ligand to metal and the coordinating ability of anions was observed. [Ag(NO 2)(L)] has a unique sheet structure consisting of double helices, and [Ag 3(L) 4](NO 3) 3 is a 2 nm thick interwoven sheet structure consisting of nanotubes. The compound [Ag 2(L) 3](CF 3SO 3) 2 affords a characteristic ladder-type channel structure, and [Ag(L) 2](PF 6) is a simple 2D grid structure.",

author = "Lee, \{Jung Woon\} and Kim, \{Eun Ae\} and Kim, \{Yun Du\} and Lee, \{Young A.\} and Youngshang Pak and Jung, \{Ok Sang\}",

year = "2005",

month = may,

day = "2",

doi = "10.1021/ic048537r",

language = "English",

volume = "44",

pages = "3151--3155",

journal = "Inorganic Chemistry",

issn = "0020-1669",

number = "9",

}

Relationship between the ratio of ligand to metal and the coordinating ability of anions. Synthesis and structural properties of AgX-bearing bis(4-pyridyl)dimethylsilane (X ^- = NO ₂ ^-, NO ₃ ^-, CF ₃so ₃ ^-, and PF ₆ ^-). / Lee, Jung Woon; Kim, Eun Ae; Kim, Yun Du et al.
In: Inorganic Chemistry, Vol. 44, No. 9, 02.05.2005, p. 3151-3155.

Research output: Contribution to journal › Journal article › peer-review

TY - JOUR

T1 - Relationship between the ratio of ligand to metal and the coordinating ability of anions. Synthesis and structural properties of AgX-bearing bis(4-pyridyl)dimethylsilane (X - = NO 2 -, NO 3 -, CF 3so 3 -, and PF 6 -)

AU - Lee, Jung Woon

AU - Kim, Eun Ae

AU - Kim, Yun Du

AU - Lee, Young A.

AU - Pak, Youngshang

AU - Jung, Ok Sang

PY - 2005/5/2

Y1 - 2005/5/2

N2 - Studies of the anion effects on the molecular construction of a series of AgX complexes with bis(4-pyridyl)-dimethylsilane (L) (X - = NO 2 -, NO 3 -, CF 3SO 3, and PF 6 -) have been carried out. Formation of the skeletal bonds appears to be primarily associated with a suitable combination of bidentate N-donors of L and a variety of coordination geometries of Ag(I) ions. The L:Ag(I) ratios of the products are dependent on the nature of the polyatomic anions. The 1:1 adduct Ag(I)-L for NO 2 -, 3:4 adduct for NO 3 -, 2:3 adduct for CF 3SO 3 -, and 1:2 adduct for PF 6 - have been obtained. A linear relationship between the ratio of ligand to metal and the coordinating ability of anions was observed. [Ag(NO 2)(L)] has a unique sheet structure consisting of double helices, and [Ag 3(L) 4](NO 3) 3 is a 2 nm thick interwoven sheet structure consisting of nanotubes. The compound [Ag 2(L) 3](CF 3SO 3) 2 affords a characteristic ladder-type channel structure, and [Ag(L) 2](PF 6) is a simple 2D grid structure.

AB - Studies of the anion effects on the molecular construction of a series of AgX complexes with bis(4-pyridyl)-dimethylsilane (L) (X - = NO 2 -, NO 3 -, CF 3SO 3, and PF 6 -) have been carried out. Formation of the skeletal bonds appears to be primarily associated with a suitable combination of bidentate N-donors of L and a variety of coordination geometries of Ag(I) ions. The L:Ag(I) ratios of the products are dependent on the nature of the polyatomic anions. The 1:1 adduct Ag(I)-L for NO 2 -, 3:4 adduct for NO 3 -, 2:3 adduct for CF 3SO 3 -, and 1:2 adduct for PF 6 - have been obtained. A linear relationship between the ratio of ligand to metal and the coordinating ability of anions was observed. [Ag(NO 2)(L)] has a unique sheet structure consisting of double helices, and [Ag 3(L) 4](NO 3) 3 is a 2 nm thick interwoven sheet structure consisting of nanotubes. The compound [Ag 2(L) 3](CF 3SO 3) 2 affords a characteristic ladder-type channel structure, and [Ag(L) 2](PF 6) is a simple 2D grid structure.

UR - https://www.scopus.com/pages/publications/19944393910

U2 - 10.1021/ic048537r

DO - 10.1021/ic048537r

M3 - Journal article

AN - SCOPUS:19944393910

SN - 0020-1669

VL - 44

SP - 3151

EP - 3155

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 9

ER -