Reversible α-elimination in the conversion of N-CH3 to N-CH=Ir by double C-H activation

D. H. Lee; J. Chen; J. W. Faller; R. H. Crabtree

doi:10.1039/b007679l

Reversible α-elimination in the conversion of N-CH₃ to N-CH=Ir by double C-H activation

D. H. Lee^*
, J. Chen
, J. W. Faller
, R. H. Crabtree

^*Corresponding author for this work

Department of Chemistry

Jeonbuk National University

Research output: Contribution to journal › Journal article › peer-review

76 Scopus citations

Abstract

2-Dimethylaminopyridine (pyNMe₂; py = 2-pyridyl) reacts with [H₂Ir(OCMe₂)₂L₂]+ (L = PPh₃) to give acyclic carbene complex [H₂Ir(=CHN(Me)py)L₂]+ via an oxidative addition, reversible α-elimination sequence.

Original language	English
Pages (from-to)	213-214
Number of pages	2
Journal	Chemical Communications
Issue number	2
DOIs	https://doi.org/10.1039/b007679l
State	Published - 2001.01.21

Quacquarelli Symonds(QS) Subject Topics

Materials Science
Engineering - Petroleum
Engineering - Chemical
Chemistry

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10.1039/b007679l

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@article{ef52bf9222b042a8bda78b47e2bb6f48,

title = "Reversible α-elimination in the conversion of N-CH3 to N-CH=Ir by double C-H activation",

abstract = "2-Dimethylaminopyridine (pyNMe2; py = 2-pyridyl) reacts with [H2Ir(OCMe2)2L2]+ (L = PPh3) to give acyclic carbene complex [H2Ir(=CHN(Me)py)L2]+ via an oxidative addition, reversible α-elimination sequence.",

author = "Lee, \{D. H.\} and J. Chen and Faller, \{J. W.\} and Crabtree, \{R. H.\}",

year = "2001",

month = jan,

day = "21",

doi = "10.1039/b007679l",

language = "English",

pages = "213--214",

journal = "Chemical Communications",

issn = "1359-7345",

number = "2",

}

TY - JOUR

T1 - Reversible α-elimination in the conversion of N-CH3 to N-CH=Ir by double C-H activation

AU - Lee, D. H.

AU - Chen, J.

AU - Faller, J. W.

AU - Crabtree, R. H.

PY - 2001/1/21

Y1 - 2001/1/21

N2 - 2-Dimethylaminopyridine (pyNMe2; py = 2-pyridyl) reacts with [H2Ir(OCMe2)2L2]+ (L = PPh3) to give acyclic carbene complex [H2Ir(=CHN(Me)py)L2]+ via an oxidative addition, reversible α-elimination sequence.

AB - 2-Dimethylaminopyridine (pyNMe2; py = 2-pyridyl) reacts with [H2Ir(OCMe2)2L2]+ (L = PPh3) to give acyclic carbene complex [H2Ir(=CHN(Me)py)L2]+ via an oxidative addition, reversible α-elimination sequence.

UR - https://www.scopus.com/pages/publications/0035924961

U2 - 10.1039/b007679l

DO - 10.1039/b007679l

M3 - Journal article

AN - SCOPUS:0035924961

SN - 1359-7345

SP - 213

EP - 214

JO - Chemical Communications

JF - Chemical Communications

IS - 2

ER -

Reversible α-elimination in the conversion of N-CH₃ to N-CH=Ir by double C-H activation

Abstract

Quacquarelli Symonds(QS) Subject Topics

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