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Reversible supra-channel effects: 3D kagome structure and catalysis via a molecular array of 1D coordination polymers

  • Haeri Lee
  • , Tae Hwan Noh
  • , Ok Sang Jung*
  • *Corresponding author for this work
  • Pusan National University

Research output: Contribution to journalJournal articlepeer-review

Abstract

Self-assembly of CuX2 (X = ClO4 and BF4) with 2,3-bis(nicotinoyloxy)naphthalene yields a 1D loop-chain skeleton. The loop-chains form an ensemble constituting a unique 3D kagome-type structure with both hexagonal and trigonal supra-channels. The unprecedented supra-channel effects on the catalytic oxidation of 3,5-di-tert-butylcatechol to 3,5-di-tert-butylbenzoquinone were investigated.

Original languageEnglish
Pages (from-to)9182-9184
Number of pages3
JournalChemical Communications
Volume49
Issue number80
DOIs
StatePublished - 2013.09.12

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