Role of carbon fiber electrodes and carbonate electrolytes in electrochemical phenol oxidation

In-situ chemical oxidation (ISCO) requires an injection of oxidants into a contaminated site. However, the oxidants decompose and react with contaminants during transport to the contaminated region, which causes oxidant over-consumption. In-situ oxidant generation can solve this problem, and electrochemical methods can be applied to achieve this. Electrochemical oxidation is highly dependent on electrode material type. In this study, we evaluated graphite and carbon fiber as candidates for electrochemical oxidant generation and phenol as the model compound. The carbon fiber anode oxidized the phenol more effectively than graphite, with removal proportional to the applied current. Carbonate electrolytes were more effective at oxidizing phenols than sulfate electrolytes. The faster carbon fiber anode phenol oxidation is due to its large surface area. Carbonate radicals in the carbonate electrolyte contribute to phenol oxidation as well as further intermediate oxidation. The carbon fiber cathode was not an effective phenol oxidizer even though it generated more hydrogen peroxide. This is because there was no catalyst to transform the hydrogen peroxide into hydroxyl radicals. Results indicate that electrochemical oxidation using carbon fiber is an effective method for treating phenol found in groundwater with high concentrations of (bi)carbonate.