Salt-activated phenolic resin/PAN-derived core-sheath nanostructured carbon nanofiber composites for capacitive energy storage

Danyun Lei; Xiang Dan Li; Min Jung Ma; Da Young Kim; Jae Hyun Noh; Byoung Suhk Kim

doi:10.1007/s42823-022-00451-6

Salt-activated phenolic resin/PAN-derived core-sheath nanostructured carbon nanofiber composites for capacitive energy storage

Danyun Lei^*
, Xiang Dan Li
, Min Jung Ma
, Da Young Kim
, Jae Hyun Noh
, Byoung Suhk Kim^*

^*Corresponding author for this work

Department of Organic Materials and Textile Engineering

Wuchang Shouyi University
South-Central University for Nationalities
Jeonbuk National University

Research output: Contribution to journal › Journal article › peer-review

12 Scopus citations

Abstract

In this study, we have fabricated the phenolic resin (PR)/polyacrylonitrile (PAN) blend-derived core-sheath nanostructured carbon nanofibers (CNFs) via one-pot solution electrospinning. The obtained core-sheath nanostructured carbon nanofibers were further treated by mixed salt activation process to develop the activated porous CNFs (CNF-A). Compared to pure PAN-based CNFs, the activated PR/PAN blend with PR 20% (CNF28-A)-derived core-sheath nanostructured CNFs showed enhanced specific capacitance of ~ 223 F g⁻¹ under a three-electrode configuration. Besides, the assembled symmetric CNF28-A//CNF28-A device possessed a specific capacitance of 76.7 F g⁻¹ at a current density of 1 A g⁻¹ and exhibited good stability of 111% after 5,000 galvanostatic charge/discharge (GCD) cycles, which verifies the outstanding long-term cycle stability of the device. Moreover, the fabricated supercapacitor device delivered an energy density of 8.63 Wh kg⁻¹ at a power density of 450 W kg⁻¹.

Original language	English
Pages (from-to)	699-711
Number of pages	13
Journal	Carbon Letters
Volume	33
Issue number	3
DOIs	https://doi.org/10.1007/s42823-022-00451-6
State	Published - 2023.05

Keywords

Activated carbon nanofiber
Mixed salt activation
Phenolic resin
Polyacrylonitrile

Quacquarelli Symonds(QS) Subject Topics

Materials Science
Engineering - Electrical & Electronic
Engineering - Petroleum
Engineering - Chemical
Chemistry

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10.1007/s42823-022-00451-6

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@article{a4455e90f4d54f75847880feba73b783,

title = "Salt-activated phenolic resin/PAN-derived core-sheath nanostructured carbon nanofiber composites for capacitive energy storage",

abstract = "In this study, we have fabricated the phenolic resin (PR)/polyacrylonitrile (PAN) blend-derived core-sheath nanostructured carbon nanofibers (CNFs) via one-pot solution electrospinning. The obtained core-sheath nanostructured carbon nanofibers were further treated by mixed salt activation process to develop the activated porous CNFs (CNF-A). Compared to pure PAN-based CNFs, the activated PR/PAN blend with PR 20\% (CNF28-A)-derived core-sheath nanostructured CNFs showed enhanced specific capacitance of \textasciitilde{} 223 F g−1 under a three-electrode configuration. Besides, the assembled symmetric CNF28-A//CNF28-A device possessed a specific capacitance of 76.7 F g−1 at a current density of 1 A g−1 and exhibited good stability of 111\% after 5,000 galvanostatic charge/discharge (GCD) cycles, which verifies the outstanding long-term cycle stability of the device. Moreover, the fabricated supercapacitor device delivered an energy density of 8.63 Wh kg−1 at a power density of 450 W kg−1.",

keywords = "Activated carbon nanofiber, Mixed salt activation, Phenolic resin, Polyacrylonitrile",

author = "Danyun Lei and Li, \{Xiang Dan\} and Ma, \{Min Jung\} and Kim, \{Da Young\} and Noh, \{Jae Hyun\} and Kim, \{Byoung Suhk\}",

note = "Publisher Copyright: {\textcopyright} 2023, The Author(s), under exclusive licence to Korean Carbon Society.",

year = "2023",

month = may,

doi = "10.1007/s42823-022-00451-6",

language = "English",

volume = "33",

pages = "699--711",

journal = "Carbon Letters",

issn = "1976-4251",

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}

TY - JOUR

T1 - Salt-activated phenolic resin/PAN-derived core-sheath nanostructured carbon nanofiber composites for capacitive energy storage

AU - Lei, Danyun

AU - Li, Xiang Dan

AU - Ma, Min Jung

AU - Kim, Da Young

AU - Noh, Jae Hyun

AU - Kim, Byoung Suhk

PY - 2023/5

Y1 - 2023/5

N2 - In this study, we have fabricated the phenolic resin (PR)/polyacrylonitrile (PAN) blend-derived core-sheath nanostructured carbon nanofibers (CNFs) via one-pot solution electrospinning. The obtained core-sheath nanostructured carbon nanofibers were further treated by mixed salt activation process to develop the activated porous CNFs (CNF-A). Compared to pure PAN-based CNFs, the activated PR/PAN blend with PR 20% (CNF28-A)-derived core-sheath nanostructured CNFs showed enhanced specific capacitance of ~ 223 F g−1 under a three-electrode configuration. Besides, the assembled symmetric CNF28-A//CNF28-A device possessed a specific capacitance of 76.7 F g−1 at a current density of 1 A g−1 and exhibited good stability of 111% after 5,000 galvanostatic charge/discharge (GCD) cycles, which verifies the outstanding long-term cycle stability of the device. Moreover, the fabricated supercapacitor device delivered an energy density of 8.63 Wh kg−1 at a power density of 450 W kg−1.

AB - In this study, we have fabricated the phenolic resin (PR)/polyacrylonitrile (PAN) blend-derived core-sheath nanostructured carbon nanofibers (CNFs) via one-pot solution electrospinning. The obtained core-sheath nanostructured carbon nanofibers were further treated by mixed salt activation process to develop the activated porous CNFs (CNF-A). Compared to pure PAN-based CNFs, the activated PR/PAN blend with PR 20% (CNF28-A)-derived core-sheath nanostructured CNFs showed enhanced specific capacitance of ~ 223 F g−1 under a three-electrode configuration. Besides, the assembled symmetric CNF28-A//CNF28-A device possessed a specific capacitance of 76.7 F g−1 at a current density of 1 A g−1 and exhibited good stability of 111% after 5,000 galvanostatic charge/discharge (GCD) cycles, which verifies the outstanding long-term cycle stability of the device. Moreover, the fabricated supercapacitor device delivered an energy density of 8.63 Wh kg−1 at a power density of 450 W kg−1.

KW - Activated carbon nanofiber

KW - Mixed salt activation

KW - Phenolic resin

KW - Polyacrylonitrile

UR - https://www.scopus.com/pages/publications/85146177586

U2 - 10.1007/s42823-022-00451-6

DO - 10.1007/s42823-022-00451-6

M3 - Journal article

AN - SCOPUS:85146177586

SN - 1976-4251

VL - 33

SP - 699

EP - 711

JO - Carbon Letters

JF - Carbon Letters

IS - 3

ER -

Salt-activated phenolic resin/PAN-derived core-sheath nanostructured carbon nanofiber composites for capacitive energy storage

Abstract

Keywords

Quacquarelli Symonds(QS) Subject Topics

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