Screen Printing of Surface-Modified Barium Titanate/Polyvinylidene Fluoride Nanocomposites for High-Performance Flexible Piezoelectric Nanogenerators

Piezoelectric energy harvesters are appealing for the improvement of wearable electronics, owing to their excellent mechanical and electrical properties. Herein, screen-printed piezoelectric nanogenerators (PENGs) are developed from triethoxy(octyl)silane-coated barium titanate/polyvinylidene fluoride (TOS-BTO/PVDF) nanocomposites with excellent performance based on the important link between material, structure, and performance. In order to minimize the effect of nanofiller agglomeration, TOS-coated BTO nanoparticles are anchored onto PVDF. Thus, composites with well-distributed TOS-BTO nanoparticles exhibit fewer defects, resulting in reduced charge annihilation during charge transfer from inorganic nanoparticles to the polymer. Consequently, the screen-printed TOS-BTO/PVDF PENG exhibits a significantly enhanced output voltage of 20 V, even after 7500 cycles, and a higher power density of 15.6 μW cm⁻², which is 200 and 150% higher than those of pristine BTO/PVDF PENGs, respectively. The increased performance of TOS-BTO/PVDF PENGs is due to the enhanced compatibility between nanofillers and polymers and the resulting improvement in dielectric response. Furthermore, as-printed devices could actively adapt to human movements and displayed excellent detection capability. The screen-printed process offers excellent potential for developing flexible and high-performance piezoelectric devices in a cost-effective and sustainable way.