Selective synthesis and structural stability of anatase and rutile Ti 1-xFe xO 2 nanoparticles

Zhenlan Jin; Changin Park; S. W. Han; Bingzhi Jiang

doi:10.3938/jkps.61.222

Selective synthesis and structural stability of anatase and rutile Ti _1-xFe _xO ₂ nanoparticles

Zhenlan Jin
, Changin Park
, S. W. Han^*
, Bingzhi Jiang

^*Corresponding author for this work

Physics Education

Jeonbuk National University
Yanbian University

Research output: Contribution to journal › Journal article › peer-review

5 Scopus citations

Abstract

Anatase and rutile Ti _1-xFe _xO ₂ nanocrystals with x = 0. 0 - 0. 05 were synthesized selectively in an aqueous solution. X-ray diffraction with refinements showed that TiO ₂ crystals calcined at 500 and 800 °C were pure anatase and rutile phases, respectively. However, TiO ₂ calcined at 550 ≤ T ≤ 600 °C showed a mixture of anatase and rutile phases. Ti _1-xFe _xO ₂ nanoparticles calcined at 500 °C had a high-quality anatase structure with no extra phases while Ti _1-xFe _xO ₂ calcined at 800 °C showed mainly a rutile structure. More disorder was observed in anatase than rutile Ti _1-xFe _xO ₂ nanoparticles. The results suggest that rutile Ti _1-xFe _xO ₂ nanoparticles are more stable than anatase Ti _1-xFe _xO ₂ nanoparticles. No change was observed from anatase or rutile TiO ₂ nanoparticles when annealed at 900 °C, suggesting that both anatase and rutile TiO ₂ nanoparticles are quite stable, once TiO ₂ is crystallized.

Original language	English
Pages (from-to)	222-226
Number of pages	5
Journal	Journal of the Korean Physical Society
Volume	61
Issue number	2
DOIs	https://doi.org/10.3938/jkps.61.222
State	Published - 2012

Keywords

DMS
Solution Synthesis
Spintronics
Structure
TiFeO
TiO
XRD

Quacquarelli Symonds(QS) Subject Topics

Physics & Astronomy

Access to Document

10.3938/jkps.61.222

Cite this

@article{4556d466b39240cca0a8efcc24aad348,

title = "Selective synthesis and structural stability of anatase and rutile Ti 1-xFe xO 2 nanoparticles",

abstract = "Anatase and rutile Ti 1-xFe xO 2 nanocrystals with x = 0. 0 - 0. 05 were synthesized selectively in an aqueous solution. X-ray diffraction with refinements showed that TiO 2 crystals calcined at 500 and 800 °C were pure anatase and rutile phases, respectively. However, TiO 2 calcined at 550 ≤ T ≤ 600 °C showed a mixture of anatase and rutile phases. Ti 1-xFe xO 2 nanoparticles calcined at 500 °C had a high-quality anatase structure with no extra phases while Ti 1-xFe xO 2 calcined at 800 °C showed mainly a rutile structure. More disorder was observed in anatase than rutile Ti 1-xFe xO 2 nanoparticles. The results suggest that rutile Ti 1-xFe xO 2 nanoparticles are more stable than anatase Ti 1-xFe xO 2 nanoparticles. No change was observed from anatase or rutile TiO 2 nanoparticles when annealed at 900 °C, suggesting that both anatase and rutile TiO 2 nanoparticles are quite stable, once TiO 2 is crystallized.",

keywords = "DMS, Solution Synthesis, Spintronics, Structure, TiFeO, TiO, XRD",

author = "Zhenlan Jin and Changin Park and Han, \{S. W.\} and Bingzhi Jiang",

year = "2012",

doi = "10.3938/jkps.61.222",

language = "English",

volume = "61",

pages = "222--226",

journal = "Journal of the Korean Physical Society",

issn = "0374-4884",

number = "2",

}

TY - JOUR

T1 - Selective synthesis and structural stability of anatase and rutile Ti 1-xFe xO 2 nanoparticles

AU - Jin, Zhenlan

AU - Park, Changin

AU - Han, S. W.

AU - Jiang, Bingzhi

PY - 2012

Y1 - 2012

N2 - Anatase and rutile Ti 1-xFe xO 2 nanocrystals with x = 0. 0 - 0. 05 were synthesized selectively in an aqueous solution. X-ray diffraction with refinements showed that TiO 2 crystals calcined at 500 and 800 °C were pure anatase and rutile phases, respectively. However, TiO 2 calcined at 550 ≤ T ≤ 600 °C showed a mixture of anatase and rutile phases. Ti 1-xFe xO 2 nanoparticles calcined at 500 °C had a high-quality anatase structure with no extra phases while Ti 1-xFe xO 2 calcined at 800 °C showed mainly a rutile structure. More disorder was observed in anatase than rutile Ti 1-xFe xO 2 nanoparticles. The results suggest that rutile Ti 1-xFe xO 2 nanoparticles are more stable than anatase Ti 1-xFe xO 2 nanoparticles. No change was observed from anatase or rutile TiO 2 nanoparticles when annealed at 900 °C, suggesting that both anatase and rutile TiO 2 nanoparticles are quite stable, once TiO 2 is crystallized.

AB - Anatase and rutile Ti 1-xFe xO 2 nanocrystals with x = 0. 0 - 0. 05 were synthesized selectively in an aqueous solution. X-ray diffraction with refinements showed that TiO 2 crystals calcined at 500 and 800 °C were pure anatase and rutile phases, respectively. However, TiO 2 calcined at 550 ≤ T ≤ 600 °C showed a mixture of anatase and rutile phases. Ti 1-xFe xO 2 nanoparticles calcined at 500 °C had a high-quality anatase structure with no extra phases while Ti 1-xFe xO 2 calcined at 800 °C showed mainly a rutile structure. More disorder was observed in anatase than rutile Ti 1-xFe xO 2 nanoparticles. The results suggest that rutile Ti 1-xFe xO 2 nanoparticles are more stable than anatase Ti 1-xFe xO 2 nanoparticles. No change was observed from anatase or rutile TiO 2 nanoparticles when annealed at 900 °C, suggesting that both anatase and rutile TiO 2 nanoparticles are quite stable, once TiO 2 is crystallized.

KW - DMS

KW - Solution Synthesis

KW - Spintronics

KW - Structure

KW - TiFeO

KW - TiO

KW - XRD

UR - https://www.scopus.com/pages/publications/84866368008

U2 - 10.3938/jkps.61.222

DO - 10.3938/jkps.61.222

M3 - Journal article

AN - SCOPUS:84866368008

SN - 0374-4884

VL - 61

SP - 222

EP - 226

JO - Journal of the Korean Physical Society

JF - Journal of the Korean Physical Society

IS - 2

ER -