Solvent exchange and discrimination in crystalline state. Formation and properties of copper(II) complexes containing 2,3-bis(isonicotinoyloxy) naphthalene

Yoonjung Cho; Jeong Gyun Kim; Tae Hwan Noh; Ok Sang Jung

doi:10.1016/j.molstruc.2013.04.042

Solvent exchange and discrimination in crystalline state. Formation and properties of copper(II) complexes containing 2,3-bis(isonicotinoyloxy) naphthalene

Yoonjung Cho
, Jeong Gyun Kim
, Tae Hwan Noh
, Ok Sang Jung^*

^*Corresponding author for this work

Chemistry Education

Pusan National University

Research output: Contribution to journal › Journal article › peer-review

5 Scopus citations

Abstract

Self-assembly of copper(II) nitrate with 2,3-bis(isonicotinoyloxy) naphthalene (L) in a mixture of acetonitrile and dichloromethane produces a 30-membered discrete metallacyclodimer, [Cu(NO₃)₂(L)]2, while the self-assembly in a mixture ofN,N-dimethylformamide and CH ₂Cl₂and a mixture ofN,N-dimethylformamide and dioxane yields 1D coordination polymers consisting of [Cu(NO₃) ₂(L)₂] ·4CH₂Cl₂ and [Cu(NO₃)₂(L)₂]·3dioxane, respectively. Recrystallizations of [Cu(NO₃)₂(L)]2 from N,N-dimethylformamide/CH₂Cl₂ and N,N-dimethylformamide/ dioxane lead to [Cu(NO₃)₂(L)₂] ·4CH ₂Cl₂ and [Cu(NO₃)₂(L)₂]- ·3dioxane, respectively. Constructions of the two skeletons, metallacyclodimer and 1D coordination polymer, are determined by solvents rather than synthetic methodologies. For [Cu(NO₃)₂(L) ₂] ·4CH₂Cl₂ and [Cu(NO₃) ₂(L)₂] ·3dioxane, exchange of the solvate molecules in the crystalline solids is carried out, and the 1D skeletal structure discriminates dioxane and CH₂Cl₂molecules.

Original language	English
Pages (from-to)	95-101
Number of pages	7
Journal	Journal of Molecular Structure
Volume	1047
DOIs	https://doi.org/10.1016/j.molstruc.2013.04.042
State	Published - 2013

Keywords

2,3-Bis(isonicotinoyloxy)naphthalene
Copper(II) complexes
Crystallization methods
Solvent discrimination
Solvent exchange

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10.1016/j.molstruc.2013.04.042

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@article{241d245bb3e345648643238bf71b20e2,

title = "Solvent exchange and discrimination in crystalline state. Formation and properties of copper(II) complexes containing 2,3-bis(isonicotinoyloxy) naphthalene",

abstract = "Self-assembly of copper(II) nitrate with 2,3-bis(isonicotinoyloxy) naphthalene (L) in a mixture of acetonitrile and dichloromethane produces a 30-membered discrete metallacyclodimer, [Cu(NO3)2(L)]2, while the self-assembly in a mixture ofN,N-dimethylformamide and CH 2Cl2and a mixture ofN,N-dimethylformamide and dioxane yields 1D coordination polymers consisting of [Cu(NO3) 2(L)2] ·4CH2Cl2 and [Cu(NO3)2(L)2]·3dioxane, respectively. Recrystallizations of [Cu(NO3)2(L)]2 from N,N-dimethylformamide/CH2Cl2 and N,N-dimethylformamide/ dioxane lead to [Cu(NO3)2(L)2] ·4CH 2Cl2 and [Cu(NO3)2(L)2]- ·3dioxane, respectively. Constructions of the two skeletons, metallacyclodimer and 1D coordination polymer, are determined by solvents rather than synthetic methodologies. For [Cu(NO3)2(L) 2] ·4CH2Cl2 and [Cu(NO3) 2(L)2] ·3dioxane, exchange of the solvate molecules in the crystalline solids is carried out, and the 1D skeletal structure discriminates dioxane and CH2Cl2molecules.",

keywords = "2,3-Bis(isonicotinoyloxy)naphthalene, Copper(II) complexes, Crystallization methods, Solvent discrimination, Solvent exchange",

author = "Yoonjung Cho and Kim, \{Jeong Gyun\} and Noh, \{Tae Hwan\} and Jung, \{Ok Sang\}",

year = "2013",

doi = "10.1016/j.molstruc.2013.04.042",

language = "English",

volume = "1047",

pages = "95--101",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

}

TY - JOUR

T1 - Solvent exchange and discrimination in crystalline state. Formation and properties of copper(II) complexes containing 2,3-bis(isonicotinoyloxy) naphthalene

AU - Cho, Yoonjung

AU - Kim, Jeong Gyun

AU - Noh, Tae Hwan

AU - Jung, Ok Sang

PY - 2013

Y1 - 2013

N2 - Self-assembly of copper(II) nitrate with 2,3-bis(isonicotinoyloxy) naphthalene (L) in a mixture of acetonitrile and dichloromethane produces a 30-membered discrete metallacyclodimer, [Cu(NO3)2(L)]2, while the self-assembly in a mixture ofN,N-dimethylformamide and CH 2Cl2and a mixture ofN,N-dimethylformamide and dioxane yields 1D coordination polymers consisting of [Cu(NO3) 2(L)2] ·4CH2Cl2 and [Cu(NO3)2(L)2]·3dioxane, respectively. Recrystallizations of [Cu(NO3)2(L)]2 from N,N-dimethylformamide/CH2Cl2 and N,N-dimethylformamide/ dioxane lead to [Cu(NO3)2(L)2] ·4CH 2Cl2 and [Cu(NO3)2(L)2]- ·3dioxane, respectively. Constructions of the two skeletons, metallacyclodimer and 1D coordination polymer, are determined by solvents rather than synthetic methodologies. For [Cu(NO3)2(L) 2] ·4CH2Cl2 and [Cu(NO3) 2(L)2] ·3dioxane, exchange of the solvate molecules in the crystalline solids is carried out, and the 1D skeletal structure discriminates dioxane and CH2Cl2molecules.

AB - Self-assembly of copper(II) nitrate with 2,3-bis(isonicotinoyloxy) naphthalene (L) in a mixture of acetonitrile and dichloromethane produces a 30-membered discrete metallacyclodimer, [Cu(NO3)2(L)]2, while the self-assembly in a mixture ofN,N-dimethylformamide and CH 2Cl2and a mixture ofN,N-dimethylformamide and dioxane yields 1D coordination polymers consisting of [Cu(NO3) 2(L)2] ·4CH2Cl2 and [Cu(NO3)2(L)2]·3dioxane, respectively. Recrystallizations of [Cu(NO3)2(L)]2 from N,N-dimethylformamide/CH2Cl2 and N,N-dimethylformamide/ dioxane lead to [Cu(NO3)2(L)2] ·4CH 2Cl2 and [Cu(NO3)2(L)2]- ·3dioxane, respectively. Constructions of the two skeletons, metallacyclodimer and 1D coordination polymer, are determined by solvents rather than synthetic methodologies. For [Cu(NO3)2(L) 2] ·4CH2Cl2 and [Cu(NO3) 2(L)2] ·3dioxane, exchange of the solvate molecules in the crystalline solids is carried out, and the 1D skeletal structure discriminates dioxane and CH2Cl2molecules.

KW - 2,3-Bis(isonicotinoyloxy)naphthalene

KW - Copper(II) complexes

KW - Crystallization methods

KW - Solvent discrimination

KW - Solvent exchange

UR - https://www.scopus.com/pages/publications/84878135536

U2 - 10.1016/j.molstruc.2013.04.042

DO - 10.1016/j.molstruc.2013.04.042

M3 - Journal article

AN - SCOPUS:84878135536

SN - 0022-2860

VL - 1047

SP - 95

EP - 101

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

ER -

Solvent exchange and discrimination in crystalline state. Formation and properties of copper(II) complexes containing 2,3-bis(isonicotinoyloxy) naphthalene

Abstract

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