Specific molecular container for dioxane: Ionic metallacyclodimeric palladium(II) complex

Jungmin Ahn; Kyung Hwan Park; Tae Hwan Noh; Ok Sang Jung

doi:10.1016/j.inoche.2011.09.001

Specific molecular container for dioxane: Ionic metallacyclodimeric palladium(II) complex

Jungmin Ahn
, Kyung Hwan Park
, Tae Hwan Noh
, Ok Sang Jung^*

^*Corresponding author for this work

Chemistry Education

Pusan National University

Research output: Contribution to journal › Journal article › peer-review

5 Scopus citations

Abstract

Metallacyclodimeric complex of [(Me₄en)Pd(L)] ₂(PF₆)₄ (Me₄en = N,N,N′,N′-tetramethylethylenediamine; L = 1,3-bis(4-pyridyl) tetramethyldisiloxane) is a sensitive container for dioxane via appropriate size effect. The equilibrium between the "included" and "free" dioxane species has been monitored by temperature-dependent ¹H NMR spectra.

Original language	English
Pages (from-to)	1868-1870
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	14
Issue number	12
DOIs	https://doi.org/10.1016/j.inoche.2011.09.001
State	Published - 2011.12

Keywords

1,3-Bis(4-pyridyl)tetramethyldisiloxane
1,4-Dioxane recognition
Host-guest chemistry
Metallacyclodimer
Palladium(II) complex

Access to Document

10.1016/j.inoche.2011.09.001

Cite this

@article{cdfe2fe8fbcb4b0eb53876a98dbbf624,

title = "Specific molecular container for dioxane: Ionic metallacyclodimeric palladium(II) complex",

abstract = "Metallacyclodimeric complex of [(Me4en)Pd(L)] 2(PF6)4 (Me4en = N,N,N′,N′-tetramethylethylenediamine; L = 1,3-bis(4-pyridyl) tetramethyldisiloxane) is a sensitive container for dioxane via appropriate size effect. The equilibrium between the {"}included{"} and {"}free{"} dioxane species has been monitored by temperature-dependent 1H NMR spectra.",

keywords = "1,3-Bis(4-pyridyl)tetramethyldisiloxane, 1,4-Dioxane recognition, Host-guest chemistry, Metallacyclodimer, Palladium(II) complex",

author = "Jungmin Ahn and Park, \{Kyung Hwan\} and Noh, \{Tae Hwan\} and Jung, \{Ok Sang\}",

year = "2011",

month = dec,

doi = "10.1016/j.inoche.2011.09.001",

language = "English",

volume = "14",

pages = "1868--1870",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

number = "12",

}

TY - JOUR

T1 - Specific molecular container for dioxane

T2 - Ionic metallacyclodimeric palladium(II) complex

AU - Ahn, Jungmin

AU - Park, Kyung Hwan

AU - Noh, Tae Hwan

AU - Jung, Ok Sang

PY - 2011/12

Y1 - 2011/12

N2 - Metallacyclodimeric complex of [(Me4en)Pd(L)] 2(PF6)4 (Me4en = N,N,N′,N′-tetramethylethylenediamine; L = 1,3-bis(4-pyridyl) tetramethyldisiloxane) is a sensitive container for dioxane via appropriate size effect. The equilibrium between the "included" and "free" dioxane species has been monitored by temperature-dependent 1H NMR spectra.

AB - Metallacyclodimeric complex of [(Me4en)Pd(L)] 2(PF6)4 (Me4en = N,N,N′,N′-tetramethylethylenediamine; L = 1,3-bis(4-pyridyl) tetramethyldisiloxane) is a sensitive container for dioxane via appropriate size effect. The equilibrium between the "included" and "free" dioxane species has been monitored by temperature-dependent 1H NMR spectra.

KW - 1,3-Bis(4-pyridyl)tetramethyldisiloxane

KW - 1,4-Dioxane recognition

KW - Host-guest chemistry

KW - Metallacyclodimer

KW - Palladium(II) complex

UR - https://www.scopus.com/pages/publications/80755153658

U2 - 10.1016/j.inoche.2011.09.001

DO - 10.1016/j.inoche.2011.09.001

M3 - Journal article

AN - SCOPUS:80755153658

SN - 1387-7003

VL - 14

SP - 1868

EP - 1870

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 12

ER -

Specific molecular container for dioxane: Ionic metallacyclodimeric palladium(II) complex

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this