Stepwise formation of cyclodimer and cage via decomposition of hexafluorophosphate anion. Structures and related properties of (2,2′-bipyridine)palladium(II) complexes of 1,3,5-tris(nicotinoyloxyethyl) cyanurate

Tae Hwan Noh; Haeri Lee; Young A. Lee; Ok Sang Jung

doi:10.1016/j.ica.2013.04.049

Stepwise formation of cyclodimer and cage via decomposition of hexafluorophosphate anion. Structures and related properties of (2,2′-bipyridine)palladium(II) complexes of 1,3,5-tris(nicotinoyloxyethyl) cyanurate

Tae Hwan Noh
, Haeri Lee
, Young A. Lee
, Ok Sang Jung^*

^*Corresponding author for this work

Department of Chemistry

Pusan National University

Research output: Contribution to journal › Journal article › peer-review

3 Scopus citations

Abstract

Reaction of (bpy)Pd(PF₆)₂ (bpy = 2,2′- bipyridine) with new tridentate ligand 1,3,5-tris(nicotinoyloxyethyl)cyanurate (L) followed by slow evaporation of solvents allows to form amorphous microspheres consisting of [(bpy)Pd(L)]₂(PF₆)₄ without any template or additive. Recrystallization of amorphous microspheres yields, after three weeks, single crystals consisting of [(bpy) 3Pd3(μ³-HPO₄)(L)](PF₃(OH)3)·3F. Formation of the crystalline product can be induced from the decomposition of the PF₆ anions. Alternatively, direct reactions of (bpy)Pd(PF ₆)₂ with L in the presence of Na₂HPO ₄ or Na₂HAsO₄ under reflux conditions produce the same single crystals in the form of cage molecules, [(bpy)3Pd ₃(μ³-HPO₄)(L)](PF3(OH)₃) ·F and [(bpy)3Pd₃(μ³-HAsO₄)(L)] (PF3(OH)3)·3F, respectively.

Original language	English
Pages (from-to)	9-14
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	405
DOIs	https://doi.org/10.1016/j.ica.2013.04.049
State	Published - 2013

Keywords

1,3,5-Tris(nicotinoyloxyethyl)cyanurate
Hexafluorophophate
Metallacycles
Palladium(II) complexes
Trifluorotrihydroxylphosphate

Quacquarelli Symonds(QS) Subject Topics

Materials Science
Engineering - Petroleum
Chemistry

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@article{3b315f9afdf34a8bb37624c0b9ad00fc,

title = "Stepwise formation of cyclodimer and cage via decomposition of hexafluorophosphate anion. Structures and related properties of (2,2′-bipyridine)palladium(II) complexes of 1,3,5-tris(nicotinoyloxyethyl) cyanurate",

abstract = "Reaction of (bpy)Pd(PF6)2 (bpy = 2,2′- bipyridine) with new tridentate ligand 1,3,5-tris(nicotinoyloxyethyl)cyanurate (L) followed by slow evaporation of solvents allows to form amorphous microspheres consisting of [(bpy)Pd(L)]2(PF6)4 without any template or additive. Recrystallization of amorphous microspheres yields, after three weeks, single crystals consisting of [(bpy) 3Pd3(μ3-HPO4)(L)](PF3(OH)3)·3F. Formation of the crystalline product can be induced from the decomposition of the PF6 anions. Alternatively, direct reactions of (bpy)Pd(PF 6)2 with L in the presence of Na2HPO 4 or Na2HAsO4 under reflux conditions produce the same single crystals in the form of cage molecules, [(bpy)3Pd 3(μ3-HPO4)(L)](PF3(OH)3) ·F and [(bpy)3Pd3(μ3-HAsO4)(L)] (PF3(OH)3)·3F, respectively.",

keywords = "1,3,5-Tris(nicotinoyloxyethyl)cyanurate, Hexafluorophophate, Metallacycles, Palladium(II) complexes, Trifluorotrihydroxylphosphate",

author = "Noh, \{Tae Hwan\} and Haeri Lee and Lee, \{Young A.\} and Jung, \{Ok Sang\}",

year = "2013",

doi = "10.1016/j.ica.2013.04.049",

language = "English",

volume = "405",

pages = "9--14",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

}

Stepwise formation of cyclodimer and cage via decomposition of hexafluorophosphate anion. Structures and related properties of (2,2′-bipyridine)palladium(II) complexes of 1,3,5-tris(nicotinoyloxyethyl) cyanurate. / Noh, Tae Hwan; Lee, Haeri; Lee, Young A. et al.
In: Inorganica Chimica Acta, Vol. 405, 2013, p. 9-14.

Research output: Contribution to journal › Journal article › peer-review

TY - JOUR

T1 - Stepwise formation of cyclodimer and cage via decomposition of hexafluorophosphate anion. Structures and related properties of (2,2′-bipyridine)palladium(II) complexes of 1,3,5-tris(nicotinoyloxyethyl) cyanurate

AU - Noh, Tae Hwan

AU - Lee, Haeri

AU - Lee, Young A.

AU - Jung, Ok Sang

PY - 2013

Y1 - 2013

N2 - Reaction of (bpy)Pd(PF6)2 (bpy = 2,2′- bipyridine) with new tridentate ligand 1,3,5-tris(nicotinoyloxyethyl)cyanurate (L) followed by slow evaporation of solvents allows to form amorphous microspheres consisting of [(bpy)Pd(L)]2(PF6)4 without any template or additive. Recrystallization of amorphous microspheres yields, after three weeks, single crystals consisting of [(bpy) 3Pd3(μ3-HPO4)(L)](PF3(OH)3)·3F. Formation of the crystalline product can be induced from the decomposition of the PF6 anions. Alternatively, direct reactions of (bpy)Pd(PF 6)2 with L in the presence of Na2HPO 4 or Na2HAsO4 under reflux conditions produce the same single crystals in the form of cage molecules, [(bpy)3Pd 3(μ3-HPO4)(L)](PF3(OH)3) ·F and [(bpy)3Pd3(μ3-HAsO4)(L)] (PF3(OH)3)·3F, respectively.

AB - Reaction of (bpy)Pd(PF6)2 (bpy = 2,2′- bipyridine) with new tridentate ligand 1,3,5-tris(nicotinoyloxyethyl)cyanurate (L) followed by slow evaporation of solvents allows to form amorphous microspheres consisting of [(bpy)Pd(L)]2(PF6)4 without any template or additive. Recrystallization of amorphous microspheres yields, after three weeks, single crystals consisting of [(bpy) 3Pd3(μ3-HPO4)(L)](PF3(OH)3)·3F. Formation of the crystalline product can be induced from the decomposition of the PF6 anions. Alternatively, direct reactions of (bpy)Pd(PF 6)2 with L in the presence of Na2HPO 4 or Na2HAsO4 under reflux conditions produce the same single crystals in the form of cage molecules, [(bpy)3Pd 3(μ3-HPO4)(L)](PF3(OH)3) ·F and [(bpy)3Pd3(μ3-HAsO4)(L)] (PF3(OH)3)·3F, respectively.

KW - 1,3,5-Tris(nicotinoyloxyethyl)cyanurate

KW - Hexafluorophophate

KW - Metallacycles

KW - Palladium(II) complexes

KW - Trifluorotrihydroxylphosphate

UR - https://www.scopus.com/pages/publications/84885225060

U2 - 10.1016/j.ica.2013.04.049

DO - 10.1016/j.ica.2013.04.049

M3 - Journal article

AN - SCOPUS:84885225060

SN - 0020-1693

VL - 405

SP - 9

EP - 14

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Stepwise formation of cyclodimer and cage via decomposition of hexafluorophosphate anion. Structures and related properties of (2,2′-bipyridine)palladium(II) complexes of 1,3,5-tris(nicotinoyloxyethyl) cyanurate

Abstract

Keywords

Quacquarelli Symonds(QS) Subject Topics

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