Structural and optical properties of hydrogen-ion-implanted ZnO nanorods

Y. B. Lee; C. H. Kwak; S. Y. Seo; S. H. Kim; C. I. Park; B. H. Kim; S. H. Park; Yong Dae Choi; S. W. Han

doi:10.3938/jkps.56.2050

Structural and optical properties of hydrogen-ion-implanted ZnO nanorods

Y. B. Lee^*
, C. H. Kwak
, S. Y. Seo
, S. H. Kim
, C. I. Park
, B. H. Kim
, S. H. Park
, Yong Dae Choi
, S. W. Han

^*Corresponding author for this work

Physics Education

Pohang University of Science and Technology
Jeonbuk National University
Research Institute of Industrial Science & Technology, Pohang
Mokwon University

Research output: Contribution to journal › Journal article › peer-review

6 Scopus citations

Abstract

We investigated the micro-structural and the optical properties of H ⁺-ion-implanted ZnO nanorods by using X-ray absorption fine structure (XAFS) measurements at the Zn K edge and photoluminescence (PL) measurements. Vertically-aligned ZnO nanorods were synthesized using metal-organic chemical-vapor deposition and were vertically implanted with hydrogen ions (H⁺) at an energy of 90 keV and a total flux of 10¹⁶ particles/cm². Scanning electron microscopy measurements showed no detectable defects existing in the H⁺-ion-implanted ZnO nanorods. However, transmission electron microscopy measurements revealed that an amorphous phase existed, particularly near the top parts of the nanorods. X-ray diffraction and XAFS measurements provided further evidence that the nanorods had structural defects due to the H⁺-ion implantation. PL measurements showed that the transition peak intensity of the H ⁺-ion-implanted ZnO nanorods was decreased dramatically due to the ion implantation.

Original language	English
Pages (from-to)	2050-2054
Number of pages	5
Journal	Journal of the Korean Physical Society
Volume	56
Issue number	61
DOIs	https://doi.org/10.3938/jkps.56.2050
State	Published - 2010

Keywords

Hydrogen implantation
Nanorod
Photoluminescence
Structure
XAFS
ZnO

Quacquarelli Symonds(QS) Subject Topics

Physics & Astronomy

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10.3938/jkps.56.2050

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@article{d662010801e24f1291a167ef56db6251,

title = "Structural and optical properties of hydrogen-ion-implanted ZnO nanorods",

abstract = "We investigated the micro-structural and the optical properties of H +-ion-implanted ZnO nanorods by using X-ray absorption fine structure (XAFS) measurements at the Zn K edge and photoluminescence (PL) measurements. Vertically-aligned ZnO nanorods were synthesized using metal-organic chemical-vapor deposition and were vertically implanted with hydrogen ions (H+) at an energy of 90 keV and a total flux of 1016 particles/cm2. Scanning electron microscopy measurements showed no detectable defects existing in the H+-ion-implanted ZnO nanorods. However, transmission electron microscopy measurements revealed that an amorphous phase existed, particularly near the top parts of the nanorods. X-ray diffraction and XAFS measurements provided further evidence that the nanorods had structural defects due to the H+-ion implantation. PL measurements showed that the transition peak intensity of the H +-ion-implanted ZnO nanorods was decreased dramatically due to the ion implantation.",

keywords = "Hydrogen implantation, Nanorod, Photoluminescence, Structure, XAFS, ZnO",

author = "Lee, \{Y. B.\} and Kwak, \{C. H.\} and Seo, \{S. Y.\} and Kim, \{S. H.\} and Park, \{C. I.\} and Kim, \{B. H.\} and Park, \{S. H.\} and Choi, \{Yong Dae\} and Han, \{S. W.\}",

year = "2010",

doi = "10.3938/jkps.56.2050",

language = "English",

volume = "56",

pages = "2050--2054",

journal = "Journal of the Korean Physical Society",

issn = "0374-4884",

number = "61",

}

TY - JOUR

T1 - Structural and optical properties of hydrogen-ion-implanted ZnO nanorods

AU - Lee, Y. B.

AU - Kwak, C. H.

AU - Seo, S. Y.

AU - Kim, S. H.

AU - Park, C. I.

AU - Kim, B. H.

AU - Park, S. H.

AU - Choi, Yong Dae

AU - Han, S. W.

PY - 2010

Y1 - 2010

N2 - We investigated the micro-structural and the optical properties of H +-ion-implanted ZnO nanorods by using X-ray absorption fine structure (XAFS) measurements at the Zn K edge and photoluminescence (PL) measurements. Vertically-aligned ZnO nanorods were synthesized using metal-organic chemical-vapor deposition and were vertically implanted with hydrogen ions (H+) at an energy of 90 keV and a total flux of 1016 particles/cm2. Scanning electron microscopy measurements showed no detectable defects existing in the H+-ion-implanted ZnO nanorods. However, transmission electron microscopy measurements revealed that an amorphous phase existed, particularly near the top parts of the nanorods. X-ray diffraction and XAFS measurements provided further evidence that the nanorods had structural defects due to the H+-ion implantation. PL measurements showed that the transition peak intensity of the H +-ion-implanted ZnO nanorods was decreased dramatically due to the ion implantation.

AB - We investigated the micro-structural and the optical properties of H +-ion-implanted ZnO nanorods by using X-ray absorption fine structure (XAFS) measurements at the Zn K edge and photoluminescence (PL) measurements. Vertically-aligned ZnO nanorods were synthesized using metal-organic chemical-vapor deposition and were vertically implanted with hydrogen ions (H+) at an energy of 90 keV and a total flux of 1016 particles/cm2. Scanning electron microscopy measurements showed no detectable defects existing in the H+-ion-implanted ZnO nanorods. However, transmission electron microscopy measurements revealed that an amorphous phase existed, particularly near the top parts of the nanorods. X-ray diffraction and XAFS measurements provided further evidence that the nanorods had structural defects due to the H+-ion implantation. PL measurements showed that the transition peak intensity of the H +-ion-implanted ZnO nanorods was decreased dramatically due to the ion implantation.

KW - Hydrogen implantation

KW - Nanorod

KW - Photoluminescence

KW - Structure

KW - XAFS

KW - ZnO

UR - https://www.scopus.com/pages/publications/77956378473

U2 - 10.3938/jkps.56.2050

DO - 10.3938/jkps.56.2050

M3 - Journal article

AN - SCOPUS:77956378473

SN - 0374-4884

VL - 56

SP - 2050

EP - 2054

JO - Journal of the Korean Physical Society

JF - Journal of the Korean Physical Society

IS - 61

ER -

Structural and optical properties of hydrogen-ion-implanted ZnO nanorods

Abstract

Keywords

Quacquarelli Symonds(QS) Subject Topics

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