Structure and electrocatalysis of sputtered RuPt thin-film electrodes

Tae Wook Kim; Seong Ju Park; Lindsay E. Jones; Michael F. Toney; Kyung Won Park; Yung Eun Sung

doi:10.1021/jp050616g

Structure and electrocatalysis of sputtered RuPt thin-film electrodes

Tae Wook Kim
, Seong Ju Park^*
, Lindsay E. Jones
, Michael F. Toney
, Kyung Won Park
, Yung Eun Sung

^*Corresponding author for this work

Department of Flexible and Printable Electronics

Gwangju Institute of Science and Technology
Stanford Synchrotron Radiation Lightsource
Northeastern University
Seoul National University

Research output: Contribution to journal › Journal article › peer-review

15 Scopus citations

Abstract

The structural and electrochemical properties of RuPt thin-film electrodes fabricated by radio frequency (rf) magnetron sputtering have been investigated. Grazing incidence X-ray diffraction data show a transition from a face-centered cubic (fee) to hexagonal cubic-packed (hep) structure as the Ru percentage increases. The transition occurs gradually between 32 and 58% Ru, which is significantly different from the bulk RuPt phase diagram. The catalytic activity of the thin-film electrodes for methanol oxidation shows a broad peak near 40-60% Ru, consistent with previous reports. The relationship between catalytic activity and film structure is discussed and contrasted with previous investigations.

Original language	English
Pages (from-to)	12845-12849
Number of pages	5
Journal	Journal of Physical Chemistry B
Volume	109
Issue number	26
DOIs	https://doi.org/10.1021/jp050616g
State	Published - 2005.07.7

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@article{73133fe2df904194860bdf449bf9e7b4,

title = "Structure and electrocatalysis of sputtered RuPt thin-film electrodes",

abstract = "The structural and electrochemical properties of RuPt thin-film electrodes fabricated by radio frequency (rf) magnetron sputtering have been investigated. Grazing incidence X-ray diffraction data show a transition from a face-centered cubic (fee) to hexagonal cubic-packed (hep) structure as the Ru percentage increases. The transition occurs gradually between 32 and 58\% Ru, which is significantly different from the bulk RuPt phase diagram. The catalytic activity of the thin-film electrodes for methanol oxidation shows a broad peak near 40-60\% Ru, consistent with previous reports. The relationship between catalytic activity and film structure is discussed and contrasted with previous investigations.",

author = "Kim, \{Tae Wook\} and Park, \{Seong Ju\} and Jones, \{Lindsay E.\} and Toney, \{Michael F.\} and Park, \{Kyung Won\} and Sung, \{Yung Eun\}",

year = "2005",

month = jul,

day = "7",

doi = "10.1021/jp050616g",

language = "English",

volume = "109",

pages = "12845--12849",

journal = "Journal of Physical Chemistry B",

issn = "1520-6106",

number = "26",

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TY - JOUR

T1 - Structure and electrocatalysis of sputtered RuPt thin-film electrodes

AU - Kim, Tae Wook

AU - Park, Seong Ju

AU - Jones, Lindsay E.

AU - Toney, Michael F.

AU - Park, Kyung Won

AU - Sung, Yung Eun

PY - 2005/7/7

Y1 - 2005/7/7

N2 - The structural and electrochemical properties of RuPt thin-film electrodes fabricated by radio frequency (rf) magnetron sputtering have been investigated. Grazing incidence X-ray diffraction data show a transition from a face-centered cubic (fee) to hexagonal cubic-packed (hep) structure as the Ru percentage increases. The transition occurs gradually between 32 and 58% Ru, which is significantly different from the bulk RuPt phase diagram. The catalytic activity of the thin-film electrodes for methanol oxidation shows a broad peak near 40-60% Ru, consistent with previous reports. The relationship between catalytic activity and film structure is discussed and contrasted with previous investigations.

AB - The structural and electrochemical properties of RuPt thin-film electrodes fabricated by radio frequency (rf) magnetron sputtering have been investigated. Grazing incidence X-ray diffraction data show a transition from a face-centered cubic (fee) to hexagonal cubic-packed (hep) structure as the Ru percentage increases. The transition occurs gradually between 32 and 58% Ru, which is significantly different from the bulk RuPt phase diagram. The catalytic activity of the thin-film electrodes for methanol oxidation shows a broad peak near 40-60% Ru, consistent with previous reports. The relationship between catalytic activity and film structure is discussed and contrasted with previous investigations.

UR - https://www.scopus.com/pages/publications/22244432832

U2 - 10.1021/jp050616g

DO - 10.1021/jp050616g

M3 - Journal article

AN - SCOPUS:22244432832

SN - 1520-6106

VL - 109

SP - 12845

EP - 12849

JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

IS - 26

ER -

Structure and electrocatalysis of sputtered RuPt thin-film electrodes

Abstract

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