Subtle media effects on formation of unique eclipsed vs staggered double chains: 1D silver(I) coordination polymers bearing C3-tridentate ligand

Euni Kim; Haeri Lee; Tae Hwan Noh; Young A. Lee; Ok Sang Jung

doi:10.1016/j.inoche.2014.05.006

Subtle media effects on formation of unique eclipsed vs staggered double chains: 1D silver(I) coordination polymers bearing C₃-tridentate ligand

Euni Kim
, Haeri Lee
, Tae Hwan Noh
, Young A. Lee
, Ok Sang Jung^*

^*Corresponding author for this work

Department of Chemistry

Pusan National University

Research output: Contribution to journal › Journal article › peer-review

1 Scopus citations

Abstract

Self-assembly of AgX (X^- = ClO₄^- and PF₆^-) with a C₃-tridentate ligand in EtOH/CH₂Cl₂ affords a ligand-eclipsed double chain whereas the cognate reaction in H₂O/MeOH produces a ligand-staggered chain consisting of alternate cyclic and bridging moieties. The anion exchangeability and photoluminescence properties are significantly affected by the different skeletal structures.

Original language	English
Pages (from-to)	81-84
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	46
DOIs	https://doi.org/10.1016/j.inoche.2014.05.006
State	Published - 2014.08

Keywords

Anion exchangeability
Eclipsed and staggered double chains
Media effects
N,N′,N″-tris(2-pyridinylethyl)-1,3,5- benzenetricarboxamide
Photoluminescence

Quacquarelli Symonds(QS) Subject Topics

Materials Science
Engineering - Petroleum
Chemistry

Access to Document

10.1016/j.inoche.2014.05.006

Cite this

@article{e63b30c9ac0044b68b33097b7bc70d38,

title = "Subtle media effects on formation of unique eclipsed vs staggered double chains: 1D silver(I) coordination polymers bearing C3-tridentate ligand",

abstract = "Self-assembly of AgX (X- = ClO4- and PF6-) with a C3-tridentate ligand in EtOH/CH2Cl2 affords a ligand-eclipsed double chain whereas the cognate reaction in H2O/MeOH produces a ligand-staggered chain consisting of alternate cyclic and bridging moieties. The anion exchangeability and photoluminescence properties are significantly affected by the different skeletal structures.",

keywords = "Anion exchangeability, Eclipsed and staggered double chains, Media effects, N,N′,N″-tris(2-pyridinylethyl)-1,3,5- benzenetricarboxamide, Photoluminescence",

author = "Euni Kim and Haeri Lee and Noh, \{Tae Hwan\} and Lee, \{Young A.\} and Jung, \{Ok Sang\}",

year = "2014",

month = aug,

doi = "10.1016/j.inoche.2014.05.006",

language = "English",

volume = "46",

pages = "81--84",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

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TY - JOUR

T1 - Subtle media effects on formation of unique eclipsed vs staggered double chains

T2 - 1D silver(I) coordination polymers bearing C3-tridentate ligand

AU - Kim, Euni

AU - Lee, Haeri

AU - Noh, Tae Hwan

AU - Lee, Young A.

AU - Jung, Ok Sang

PY - 2014/8

Y1 - 2014/8

N2 - Self-assembly of AgX (X- = ClO4- and PF6-) with a C3-tridentate ligand in EtOH/CH2Cl2 affords a ligand-eclipsed double chain whereas the cognate reaction in H2O/MeOH produces a ligand-staggered chain consisting of alternate cyclic and bridging moieties. The anion exchangeability and photoluminescence properties are significantly affected by the different skeletal structures.

AB - Self-assembly of AgX (X- = ClO4- and PF6-) with a C3-tridentate ligand in EtOH/CH2Cl2 affords a ligand-eclipsed double chain whereas the cognate reaction in H2O/MeOH produces a ligand-staggered chain consisting of alternate cyclic and bridging moieties. The anion exchangeability and photoluminescence properties are significantly affected by the different skeletal structures.

KW - Anion exchangeability

KW - Eclipsed and staggered double chains

KW - Media effects

KW - N,N′,N″-tris(2-pyridinylethyl)-1,3,5- benzenetricarboxamide

KW - Photoluminescence

UR - https://www.scopus.com/pages/publications/84901912646

U2 - 10.1016/j.inoche.2014.05.006

DO - 10.1016/j.inoche.2014.05.006

M3 - Journal article

AN - SCOPUS:84901912646

SN - 1387-7003

VL - 46

SP - 81

EP - 84

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -