Suprachannel as a Radical Trap: Crystal Structure of Single Carbon Radicals

Yoonjung Cho; Tae Hwan Noh; Jeong Gyun Kim; Haeri Lee; Ok Sang Jung

doi:10.1021/acs.cgd.6b00318

Suprachannel as a Radical Trap: Crystal Structure of Single Carbon Radicals

Yoonjung Cho
, Tae Hwan Noh
, Jeong Gyun Kim
, Haeri Lee
, Ok Sang Jung^*

^*Corresponding author for this work

Chemistry Education

Pusan National University

Research output: Contribution to journal › Journal article › peer-review

16 Scopus citations

Abstract

We report proof-of-concept experiments on the unprecedented crystal structure of an iodomethyl radical (·CH₂I) nestled within an ensembles suprachannel via single crystal-to-single crystal photoreaction without destruction of the suprachannel. The trapped nonconjugated carbon radical was additionally confirmed by EPR, ¹³C MAS, UPS, and Raman spectra.

Original language	English
Pages (from-to)	3054-3058
Number of pages	5
Journal	Crystal Growth and Design
Volume	16
Issue number	6
DOIs	https://doi.org/10.1021/acs.cgd.6b00318
State	Published - 2016.06.1

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10.1021/acs.cgd.6b00318

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title = "Suprachannel as a Radical Trap: Crystal Structure of Single Carbon Radicals",

abstract = "We report proof-of-concept experiments on the unprecedented crystal structure of an iodomethyl radical (·CH2I) nestled within an ensembles suprachannel via single crystal-to-single crystal photoreaction without destruction of the suprachannel. The trapped nonconjugated carbon radical was additionally confirmed by EPR, 13C MAS, UPS, and Raman spectra.",

author = "Yoonjung Cho and Noh, \{Tae Hwan\} and Kim, \{Jeong Gyun\} and Haeri Lee and Jung, \{Ok Sang\}",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

month = jun,

day = "1",

doi = "10.1021/acs.cgd.6b00318",

language = "English",

volume = "16",

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journal = "Crystal Growth and Design",

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T1 - Suprachannel as a Radical Trap

T2 - Crystal Structure of Single Carbon Radicals

AU - Cho, Yoonjung

AU - Noh, Tae Hwan

AU - Kim, Jeong Gyun

AU - Lee, Haeri

AU - Jung, Ok Sang

PY - 2016/6/1

Y1 - 2016/6/1

N2 - We report proof-of-concept experiments on the unprecedented crystal structure of an iodomethyl radical (·CH2I) nestled within an ensembles suprachannel via single crystal-to-single crystal photoreaction without destruction of the suprachannel. The trapped nonconjugated carbon radical was additionally confirmed by EPR, 13C MAS, UPS, and Raman spectra.

AB - We report proof-of-concept experiments on the unprecedented crystal structure of an iodomethyl radical (·CH2I) nestled within an ensembles suprachannel via single crystal-to-single crystal photoreaction without destruction of the suprachannel. The trapped nonconjugated carbon radical was additionally confirmed by EPR, 13C MAS, UPS, and Raman spectra.

UR - https://www.scopus.com/pages/publications/84973307955

U2 - 10.1021/acs.cgd.6b00318

DO - 10.1021/acs.cgd.6b00318

M3 - Journal article

AN - SCOPUS:84973307955

SN - 1528-7483

VL - 16

SP - 3054

EP - 3058

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 6

ER -

Suprachannel as a Radical Trap: Crystal Structure of Single Carbon Radicals

Abstract

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