Suprachannels via a molecular array of 2D networks: Solvent effects, anion exchange, and physicochemical properties of silver(I) complexes bearing N,N′,N″-tris(2-pyridinylethyl)-1,3,5-benzenetricarboxamide

Euni Kim; Haeri Lee; Tae Hwan Noh; Ok Sang Jung

doi:10.1021/cg500025k

Suprachannels via a molecular array of 2D networks: Solvent effects, anion exchange, and physicochemical properties of silver(I) complexes bearing N,N′,N″-tris(2-pyridinylethyl)-1,3,5-benzenetricarboxamide

Euni Kim
, Haeri Lee
, Tae Hwan Noh
, Ok Sang Jung^*

^*Corresponding author for this work

Chemistry Education

Pusan National University

Research output: Contribution to journal › Journal article › peer-review

24 Scopus citations

Abstract

The solvent effects on suprachannel formation via a molecular array of 2D networks were studied. The basic structure of the [Ag₃L ₂](X)₃ (X^- = NO₂^-, NO₃^-) 2D network consists of hexagonal (Ag ₆L₆) motifs formed via self-assembly of Ag(I) with C ₃-tridentate N-donors. The 2D networks are arranged in an eclipsed mode in aqueous solution, thus forming suprachannels (5.2 × 7.3 Å², 6.2 × 7.7 Å²) of [Ag ₃L₂(H₂O)₂](X)₃, whereas they are arranged in a staggered abab... mode in nonaqueous solution, thus forming semisuprachannels (3.1 × 5.1 Å²) of [Ag ₃(NO₃)₂L₂](NO₃). The suprachannel structure of [Ag₃L₂(H₂O) ₂](NO₃)₃ is soluble in methanol; contrastingly, the semisuprachannel structure of [Ag₃(NO₃) ₂L₂](NO₃) is insoluble in that solvent. In the present study, significant differences in molecular recognition and anion exchangeability between [Ag₃L₂(H₂O) ₂](NO₃)₃ and [Ag₃(NO ₃)₂L₂](NO₃) were found.

Original language	English
Pages (from-to)	1888-1894
Number of pages	7
Journal	Crystal Growth and Design
Volume	14
Issue number	4
DOIs	https://doi.org/10.1021/cg500025k
State	Published - 2014.04.2

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@article{798e5706bd28427499d5d81de1835eb3,

title = "Suprachannels via a molecular array of 2D networks: Solvent effects, anion exchange, and physicochemical properties of silver(I) complexes bearing N,N′,N″-tris(2-pyridinylethyl)-1,3,5-benzenetricarboxamide",

abstract = "The solvent effects on suprachannel formation via a molecular array of 2D networks were studied. The basic structure of the [Ag3L 2](X)3 (X- = NO2-, NO3-) 2D network consists of hexagonal (Ag 6L6) motifs formed via self-assembly of Ag(I) with C 3-tridentate N-donors. The 2D networks are arranged in an eclipsed mode in aqueous solution, thus forming suprachannels (5.2 × 7.3 {\AA}2, 6.2 × 7.7 {\AA}2) of [Ag 3L2(H2O)2](X)3, whereas they are arranged in a staggered abab... mode in nonaqueous solution, thus forming semisuprachannels (3.1 × 5.1 {\AA}2) of [Ag 3(NO3)2L2](NO3). The suprachannel structure of [Ag3L2(H2O) 2](NO3)3 is soluble in methanol; contrastingly, the semisuprachannel structure of [Ag3(NO3) 2L2](NO3) is insoluble in that solvent. In the present study, significant differences in molecular recognition and anion exchangeability between [Ag3L2(H2O) 2](NO3)3 and [Ag3(NO 3)2L2](NO3) were found.",

author = "Euni Kim and Haeri Lee and Noh, \{Tae Hwan\} and Jung, \{Ok Sang\}",

year = "2014",

month = apr,

day = "2",

doi = "10.1021/cg500025k",

language = "English",

volume = "14",

pages = "1888--1894",

journal = "Crystal Growth and Design",

issn = "1528-7483",

number = "4",

}

Suprachannels via a molecular array of 2D networks: Solvent effects, anion exchange, and physicochemical properties of silver(I) complexes bearing N,N′,N″-tris(2-pyridinylethyl)-1,3,5-benzenetricarboxamide. / Kim, Euni; Lee, Haeri; Noh, Tae Hwan et al.
In: Crystal Growth and Design, Vol. 14, No. 4, 02.04.2014, p. 1888-1894.

Research output: Contribution to journal › Journal article › peer-review

TY - JOUR

T1 - Suprachannels via a molecular array of 2D networks

T2 - Solvent effects, anion exchange, and physicochemical properties of silver(I) complexes bearing N,N′,N″-tris(2-pyridinylethyl)-1,3,5-benzenetricarboxamide

AU - Kim, Euni

AU - Lee, Haeri

AU - Noh, Tae Hwan

AU - Jung, Ok Sang

PY - 2014/4/2

Y1 - 2014/4/2

N2 - The solvent effects on suprachannel formation via a molecular array of 2D networks were studied. The basic structure of the [Ag3L 2](X)3 (X- = NO2-, NO3-) 2D network consists of hexagonal (Ag 6L6) motifs formed via self-assembly of Ag(I) with C 3-tridentate N-donors. The 2D networks are arranged in an eclipsed mode in aqueous solution, thus forming suprachannels (5.2 × 7.3 Å2, 6.2 × 7.7 Å2) of [Ag 3L2(H2O)2](X)3, whereas they are arranged in a staggered abab... mode in nonaqueous solution, thus forming semisuprachannels (3.1 × 5.1 Å2) of [Ag 3(NO3)2L2](NO3). The suprachannel structure of [Ag3L2(H2O) 2](NO3)3 is soluble in methanol; contrastingly, the semisuprachannel structure of [Ag3(NO3) 2L2](NO3) is insoluble in that solvent. In the present study, significant differences in molecular recognition and anion exchangeability between [Ag3L2(H2O) 2](NO3)3 and [Ag3(NO 3)2L2](NO3) were found.

AB - The solvent effects on suprachannel formation via a molecular array of 2D networks were studied. The basic structure of the [Ag3L 2](X)3 (X- = NO2-, NO3-) 2D network consists of hexagonal (Ag 6L6) motifs formed via self-assembly of Ag(I) with C 3-tridentate N-donors. The 2D networks are arranged in an eclipsed mode in aqueous solution, thus forming suprachannels (5.2 × 7.3 Å2, 6.2 × 7.7 Å2) of [Ag 3L2(H2O)2](X)3, whereas they are arranged in a staggered abab... mode in nonaqueous solution, thus forming semisuprachannels (3.1 × 5.1 Å2) of [Ag 3(NO3)2L2](NO3). The suprachannel structure of [Ag3L2(H2O) 2](NO3)3 is soluble in methanol; contrastingly, the semisuprachannel structure of [Ag3(NO3) 2L2](NO3) is insoluble in that solvent. In the present study, significant differences in molecular recognition and anion exchangeability between [Ag3L2(H2O) 2](NO3)3 and [Ag3(NO 3)2L2](NO3) were found.

UR - https://www.scopus.com/pages/publications/84897482242

U2 - 10.1021/cg500025k

DO - 10.1021/cg500025k

M3 - Journal article

AN - SCOPUS:84897482242

SN - 1528-7483

VL - 14

SP - 1888

EP - 1894

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 4

ER -

Suprachannels via a molecular array of 2D networks: Solvent effects, anion exchange, and physicochemical properties of silver(I) complexes bearing N,N′,N″-tris(2-pyridinylethyl)-1,3,5-benzenetricarboxamide

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