Supramolecular framework with two different kinds of channels via self-assembly of 1D coordination polymers in a prismatic manner

Il Park Byung; Sung Chun In; Young A. Lee; Ki Min Park; Ok Sang Jung

doi:10.1021/ic052053t

Supramolecular framework with two different kinds of channels via self-assembly of 1D coordination polymers in a prismatic manner

Il Park Byung
, Sung Chun In
, Young A. Lee
, Ki Min Park
, Ok Sang Jung^*

^*Corresponding author for this work

Department of Chemistry

Pusan National University
Gyeongsang National University

Research output: Contribution to journal › Journal article › peer-review

32 Scopus citations

Abstract

Slow diffusion of Cu(ClO₄)₂ with p-C ₆H₄(SiMe₂(4-Py))₂ yields a supramolecular framework consisting of two kinds of channels via self-assembly of a 1D double-stranded chain in a prismatic fashion. The channel has a 11 x 11 Å² cross section (Cu⋯C = 11.13 Å) with a 6 x 6 Å² square pore. The channels are infinitely arranged, resulting in another kind of channel with similar pores. Thus, two different kinds of channels with different solvate molecules coexist in a 1:2 ratio. Weak C-H⋯π interaction may be one of the driving forces in the assembly of the prismatic channel structure.

Original language	English
Pages (from-to)	4310-4312
Number of pages	3
Journal	Inorganic Chemistry
Volume	45
Issue number	11
DOIs	https://doi.org/10.1021/ic052053t
State	Published - 2006.05.29

Quacquarelli Symonds(QS) Subject Topics

Engineering - Petroleum
Chemistry

Access to Document

10.1021/ic052053t

Cite this

@article{dcbceebfba714b56bfc37ad9be857f85,

title = "Supramolecular framework with two different kinds of channels via self-assembly of 1D coordination polymers in a prismatic manner",

abstract = "Slow diffusion of Cu(ClO4)2 with p-C 6H4(SiMe2(4-Py))2 yields a supramolecular framework consisting of two kinds of channels via self-assembly of a 1D double-stranded chain in a prismatic fashion. The channel has a 11 x 11 {\AA}2 cross section (Cu⋯C = 11.13 {\AA}) with a 6 x 6 {\AA}2 square pore. The channels are infinitely arranged, resulting in another kind of channel with similar pores. Thus, two different kinds of channels with different solvate molecules coexist in a 1:2 ratio. Weak C-H⋯π interaction may be one of the driving forces in the assembly of the prismatic channel structure.",

author = "Byung, \{Il Park\} and In, \{Sung Chun\} and Lee, \{Young A.\} and Park, \{Ki Min\} and Jung, \{Ok Sang\}",

year = "2006",

month = may,

day = "29",

doi = "10.1021/ic052053t",

language = "English",

volume = "45",

pages = "4310--4312",

journal = "Inorganic Chemistry",

issn = "0020-1669",

number = "11",

}

TY - JOUR

T1 - Supramolecular framework with two different kinds of channels via self-assembly of 1D coordination polymers in a prismatic manner

AU - Byung, Il Park

AU - In, Sung Chun

AU - Lee, Young A.

AU - Park, Ki Min

AU - Jung, Ok Sang

PY - 2006/5/29

Y1 - 2006/5/29

N2 - Slow diffusion of Cu(ClO4)2 with p-C 6H4(SiMe2(4-Py))2 yields a supramolecular framework consisting of two kinds of channels via self-assembly of a 1D double-stranded chain in a prismatic fashion. The channel has a 11 x 11 Å2 cross section (Cu⋯C = 11.13 Å) with a 6 x 6 Å2 square pore. The channels are infinitely arranged, resulting in another kind of channel with similar pores. Thus, two different kinds of channels with different solvate molecules coexist in a 1:2 ratio. Weak C-H⋯π interaction may be one of the driving forces in the assembly of the prismatic channel structure.

AB - Slow diffusion of Cu(ClO4)2 with p-C 6H4(SiMe2(4-Py))2 yields a supramolecular framework consisting of two kinds of channels via self-assembly of a 1D double-stranded chain in a prismatic fashion. The channel has a 11 x 11 Å2 cross section (Cu⋯C = 11.13 Å) with a 6 x 6 Å2 square pore. The channels are infinitely arranged, resulting in another kind of channel with similar pores. Thus, two different kinds of channels with different solvate molecules coexist in a 1:2 ratio. Weak C-H⋯π interaction may be one of the driving forces in the assembly of the prismatic channel structure.

UR - https://www.scopus.com/pages/publications/33745711791

U2 - 10.1021/ic052053t

DO - 10.1021/ic052053t

M3 - Journal article

AN - SCOPUS:33745711791

SN - 0020-1669

VL - 45

SP - 4310

EP - 4312

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 11

ER -

Supramolecular framework with two different kinds of channels via self-assembly of 1D coordination polymers in a prismatic manner

Abstract

Quacquarelli Symonds(QS) Subject Topics

Access to Document

Other files and links

Fingerprint

Cite this