Synthesis and characterization of partially fluorinated sulfonated poly(arylene biphenylsulfone ketone) block copolymers containing 6F-BPA and perfluorobiphenylene units

A new series of partially fluorinated and sulfonated poly(biphenylsulfone ketone) block copolymers as proton exchange membrane materials were prepared from hydrophilic and hydrophobic oligomers. The copolymers were characterized by proton NMR, FT-IR, GPC, thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC) thermograms. The membranes showed excellent thermal and oxidative stability; e.g., TGA and DSC demonstrated that all sulfonated block copolymers exhibited good thermal stability with an initial weight loss at temperatures above 200 °C. Block-30 membranes showed low water uptake and acceptable ionic exchange capacity (IEC). The proton conductivity of the block-30 was 75 mS cm^-1 at 90 °C and 100% relative humidity (RH), while Nafion-117 had a value of 98 mS cm^-1 under the same conditions. AFM analysis of the Block-30 clearly showed that the morphology of the membranes separated the hydrophilic and hydrophobic domains which provided an effective proton-transport pathway.