Synthesis and characterization of polyanhydride for local BCNU delivery carriers

  • Suk Kim Moon
  • , Su Seo Kwang
  • , Soo Seong Ha
  • , Hang Cho Sun
  • , Bang Lee Hai*
  • , Duck Hong Keum
  • , Kyung Kim Sun
  • , Gilson Khang
  • *Corresponding author for this work

Research output: Contribution to journalJournal articlepeer-review

Abstract

p-Carboxyphenoxy propane (CPP) prepolymer consisting of 4 units and sebacic acid (SA) prepolymer consisting of about 10 units were synthesized by reacting CPP and SA in the presence of excess acetic anhydride, respectively. Polyanhydride, poly(CPP-SA) copolymers were copolymerized by a melt polycondensation process with a mixture of CPP and SA prepolymer. Copolymers of average molecular weight up to 110,000 g/mol were achieved. The crystallinity of poly(CPP-SA) copolymers was decreased by the addition of the CPP homopolymer segment to SA homopolymer. Poly(CPP-SA) copolymers gradually degraded for period of 10 days. No large difference of weight loss observed according to molecular weight variation of poly(CPP-SA) copolymers. BCNU release from wafers fabricated by poly(CPP-SA) showed a sustained release pattern with no initial burst and delay of drug release.

Original languageEnglish
Pages (from-to)229-238
Number of pages10
JournalBio-Medical Materials and Engineering
Volume15
Issue number3
StatePublished - 2005

Keywords

  • BCNU
  • Polyanhydride
  • Polycondensation
  • Sustained drug release

Quacquarelli Symonds(QS) Subject Topics

  • Materials Science
  • Biological Sciences

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