Synthesis and characterization of spherical morphology [Ni0.4Co0.2Mn0.4]3O4 materials for lithium secondary batteries

Sung Woo Oh; Sang Ho Park; K. Amine; Yang Kook Sun

doi:10.1016/j.jpowsour.2006.01.023

Synthesis and characterization of spherical morphology [Ni_0.4Co_0.2Mn_0.4]₃O₄ materials for lithium secondary batteries

Sung Woo Oh
, Sang Ho Park
, K. Amine
, Yang Kook Sun^*

^*Corresponding author for this work

Division of Chemical Engineering

Hanyang University
Argonne National Laboratory

Research output: Contribution to journal › Journal article › peer-review

21 Scopus citations

Abstract

Spherical morphology [Ni_0.4Co_0.2Mn_0.4]₃O₄ materials have been synthesized by ultrasonic spray pyrolysis. The Li[Ni_0.4Co_0.2Mn_0.4]O₂ powders were prepared at various pyrolysis temperatures between 500 and 900 °C. The Li[Ni_0.4Co_0.2Mn_0.4]O₂ material prepared at a pyrolysis temperature of 600 °C samples are exhibited excellent electrochemical cycling performance and delivered the highest discharge capacity at over 180 mAh g^-1 between 2.8 and 4.4 V. The structural, electrochemical, morphological property and thermal stability of the powders were characterized by X-ray diffraction (XRD), galvanostatic charge/discharge testing, scanning electron microscopy (SEM), and differential scanning calorimeter (DSC), respectively.

Original language	English
Pages (from-to)	558-562
Number of pages	5
Journal	Journal of Power Sources
Volume	160
Issue number	1
DOIs	https://doi.org/10.1016/j.jpowsour.2006.01.023
State	Published - 2006.09.29

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Electrochemical properties
Layered materials
Lithium secondary batteries
Positive materials
Spray pyrolysis

Access to Document

10.1016/j.jpowsour.2006.01.023

Cite this

@article{814f60cf7f4f4ebfac76617f2b4f05a2,

title = "Synthesis and characterization of spherical morphology [Ni0.4Co0.2Mn0.4]3O4 materials for lithium secondary batteries",

abstract = "Spherical morphology [Ni0.4Co0.2Mn0.4]3O4 materials have been synthesized by ultrasonic spray pyrolysis. The Li[Ni0.4Co0.2Mn0.4]O2 powders were prepared at various pyrolysis temperatures between 500 and 900 °C. The Li[Ni0.4Co0.2Mn0.4]O2 material prepared at a pyrolysis temperature of 600 °C samples are exhibited excellent electrochemical cycling performance and delivered the highest discharge capacity at over 180 mAh g-1 between 2.8 and 4.4 V. The structural, electrochemical, morphological property and thermal stability of the powders were characterized by X-ray diffraction (XRD), galvanostatic charge/discharge testing, scanning electron microscopy (SEM), and differential scanning calorimeter (DSC), respectively.",

keywords = "Electrochemical properties, Layered materials, Lithium secondary batteries, Positive materials, Spray pyrolysis",

author = "Oh, \{Sung Woo\} and Park, \{Sang Ho\} and K. Amine and Sun, \{Yang Kook\}",

year = "2006",

month = sep,

day = "29",

doi = "10.1016/j.jpowsour.2006.01.023",

language = "English",

volume = "160",

pages = "558--562",

journal = "Journal of Power Sources",

issn = "0378-7753",

number = "1",

}

TY - JOUR

T1 - Synthesis and characterization of spherical morphology [Ni0.4Co0.2Mn0.4]3O4 materials for lithium secondary batteries

AU - Oh, Sung Woo

AU - Park, Sang Ho

AU - Amine, K.

AU - Sun, Yang Kook

PY - 2006/9/29

Y1 - 2006/9/29

N2 - Spherical morphology [Ni0.4Co0.2Mn0.4]3O4 materials have been synthesized by ultrasonic spray pyrolysis. The Li[Ni0.4Co0.2Mn0.4]O2 powders were prepared at various pyrolysis temperatures between 500 and 900 °C. The Li[Ni0.4Co0.2Mn0.4]O2 material prepared at a pyrolysis temperature of 600 °C samples are exhibited excellent electrochemical cycling performance and delivered the highest discharge capacity at over 180 mAh g-1 between 2.8 and 4.4 V. The structural, electrochemical, morphological property and thermal stability of the powders were characterized by X-ray diffraction (XRD), galvanostatic charge/discharge testing, scanning electron microscopy (SEM), and differential scanning calorimeter (DSC), respectively.

AB - Spherical morphology [Ni0.4Co0.2Mn0.4]3O4 materials have been synthesized by ultrasonic spray pyrolysis. The Li[Ni0.4Co0.2Mn0.4]O2 powders were prepared at various pyrolysis temperatures between 500 and 900 °C. The Li[Ni0.4Co0.2Mn0.4]O2 material prepared at a pyrolysis temperature of 600 °C samples are exhibited excellent electrochemical cycling performance and delivered the highest discharge capacity at over 180 mAh g-1 between 2.8 and 4.4 V. The structural, electrochemical, morphological property and thermal stability of the powders were characterized by X-ray diffraction (XRD), galvanostatic charge/discharge testing, scanning electron microscopy (SEM), and differential scanning calorimeter (DSC), respectively.

KW - Electrochemical properties

KW - Layered materials

KW - Lithium secondary batteries

KW - Positive materials

KW - Spray pyrolysis

UR - https://www.scopus.com/pages/publications/33748435168

U2 - 10.1016/j.jpowsour.2006.01.023

DO - 10.1016/j.jpowsour.2006.01.023

M3 - Journal article

AN - SCOPUS:33748435168

SN - 0378-7753

VL - 160

SP - 558

EP - 562

JO - Journal of Power Sources

JF - Journal of Power Sources

IS - 1

ER -