Synthesis and optical properties of fluorinated poly(arylene ether phosphine oxide)s

Jae Pil Kim; Jae Wook Kang; Jang Joo Kim; Jae Suk Lee

doi:10.1002/pola.10694

Synthesis and optical properties of fluorinated poly(arylene ether phosphine oxide)s

Jae Pil Kim
, Jae Wook Kang
, Jang Joo Kim
, Jae Suk Lee^*

^*Corresponding author for this work

Department of Flexible and Printable Electronics

Gwangju Institute of Science and Technology

Research output: Contribution to journal › Journal article › peer-review

29 Scopus citations

Abstract

Fluorinated dihydroxy phosphine oxide monomers were synthesized via chlorination, Grignard, and demethylation techniques. The prepared monomer was successfully polymerized with each of the three perfluorinated monomers (decafluorobiphenyl, decafluorobenzophenone, and pentanuorophenylsulfide) by nucleophilic aromatic substitution. The average molecular weight ranged between 7800 and 14,900 g/mol. The glass-transition temperatures of the polymers were registered in the range of 185-235 °C, and all the polymers exhibited high thermal stability up to 326-408 °C. The results of the refractive-index measurements indicated control of the refractive index between 1.5181 and 1.5536 and an optical loss of 0.53 dB/cm at 1550 nm.

Original language	English
Pages (from-to)	1497-1503
Number of pages	7
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	41
Issue number	10
DOIs	https://doi.org/10.1002/pola.10694
State	Published - 2003.05.15

Keywords

Halogenated
Optical loss
Poly(arylene ether phosphine oxide)
Refractive index
Step-growth polymerization

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10.1002/pola.10694

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@article{80b81c5d0eb74bb7ac1547ab8d0e8b2e,

title = "Synthesis and optical properties of fluorinated poly(arylene ether phosphine oxide)s",

abstract = "Fluorinated dihydroxy phosphine oxide monomers were synthesized via chlorination, Grignard, and demethylation techniques. The prepared monomer was successfully polymerized with each of the three perfluorinated monomers (decafluorobiphenyl, decafluorobenzophenone, and pentanuorophenylsulfide) by nucleophilic aromatic substitution. The average molecular weight ranged between 7800 and 14,900 g/mol. The glass-transition temperatures of the polymers were registered in the range of 185-235 °C, and all the polymers exhibited high thermal stability up to 326-408 °C. The results of the refractive-index measurements indicated control of the refractive index between 1.5181 and 1.5536 and an optical loss of 0.53 dB/cm at 1550 nm.",

keywords = "Halogenated, Optical loss, Poly(arylene ether phosphine oxide), Refractive index, Step-growth polymerization",

author = "Kim, \{Jae Pil\} and Kang, \{Jae Wook\} and Kim, \{Jang Joo\} and Lee, \{Jae Suk\}",

year = "2003",

month = may,

day = "15",

doi = "10.1002/pola.10694",

language = "English",

volume = "41",

pages = "1497--1503",

journal = "Journal of Polymer Science, Part A: Polymer Chemistry",

issn = "0887-624X",

number = "10",

}

TY - JOUR

T1 - Synthesis and optical properties of fluorinated poly(arylene ether phosphine oxide)s

AU - Kim, Jae Pil

AU - Kang, Jae Wook

AU - Kim, Jang Joo

AU - Lee, Jae Suk

PY - 2003/5/15

Y1 - 2003/5/15

N2 - Fluorinated dihydroxy phosphine oxide monomers were synthesized via chlorination, Grignard, and demethylation techniques. The prepared monomer was successfully polymerized with each of the three perfluorinated monomers (decafluorobiphenyl, decafluorobenzophenone, and pentanuorophenylsulfide) by nucleophilic aromatic substitution. The average molecular weight ranged between 7800 and 14,900 g/mol. The glass-transition temperatures of the polymers were registered in the range of 185-235 °C, and all the polymers exhibited high thermal stability up to 326-408 °C. The results of the refractive-index measurements indicated control of the refractive index between 1.5181 and 1.5536 and an optical loss of 0.53 dB/cm at 1550 nm.

AB - Fluorinated dihydroxy phosphine oxide monomers were synthesized via chlorination, Grignard, and demethylation techniques. The prepared monomer was successfully polymerized with each of the three perfluorinated monomers (decafluorobiphenyl, decafluorobenzophenone, and pentanuorophenylsulfide) by nucleophilic aromatic substitution. The average molecular weight ranged between 7800 and 14,900 g/mol. The glass-transition temperatures of the polymers were registered in the range of 185-235 °C, and all the polymers exhibited high thermal stability up to 326-408 °C. The results of the refractive-index measurements indicated control of the refractive index between 1.5181 and 1.5536 and an optical loss of 0.53 dB/cm at 1550 nm.

KW - Halogenated

KW - Optical loss

KW - Poly(arylene ether phosphine oxide)

KW - Refractive index

KW - Step-growth polymerization

UR - https://www.scopus.com/pages/publications/0037448081

U2 - 10.1002/pola.10694

DO - 10.1002/pola.10694

M3 - Journal article

AN - SCOPUS:0037448081

SN - 0887-624X

VL - 41

SP - 1497

EP - 1503

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

IS - 10

ER -

Synthesis and optical properties of fluorinated poly(arylene ether phosphine oxide)s

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Keywords

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