Synthesis, crystal structure, and analytical characterizations of amphiphilic palladium(II) compound containing bis(benzylthio)methylenepropanedioate

Tae Hwan Noh

doi:10.5806/AST.2023.36.4.198

Synthesis, crystal structure, and analytical characterizations of amphiphilic palladium(II) compound containing bis(benzylthio)methylenepropanedioate

Tae Hwan Noh^*

^*Corresponding author for this work

Chemistry Education

Research output: Contribution to journal › Journal article › peer-review

Abstract

The reaction of cis-protected (Me₄en)Pd(II) species with potentially multidentate bis(benzylthio)methy-lenepropanedioate (L) was carried out to obtain a monometallic compound, [(Me₄en)Pd(L)], in O,O’-coordination mode. The bis(benzylthio)methylene group was bent strikingly from the palladium square plane at the dihedral angle of 70.40°. The physicochemical properties of the present palladium(II) compound were fully characterized by means of infrared and nuclear magnetic resonance spectroscopy, thermogravimetric analysis, and single-crystal X-ray diffraction measurement.

Original language	English
Pages (from-to)	198-203
Number of pages	6
Journal	Analytical Science and Technology
Volume	36
Issue number	4
DOIs	https://doi.org/10.5806/AST.2023.36.4.198
State	Published - 2023

Keywords

coordination mode
crystal engineering
NMR spectroscopy
X-ray diffraction

Quacquarelli Symonds(QS) Subject Topics

Agriculture & Forestry
Environmental Sciences
Materials Science
Engineering - Petroleum
Pharmacy & Pharmacology
Chemistry

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title = "Synthesis, crystal structure, and analytical characterizations of amphiphilic palladium(II) compound containing bis(benzylthio)methylenepropanedioate",

abstract = "The reaction of cis-protected (Me4en)Pd(II) species with potentially multidentate bis(benzylthio)methy-lenepropanedioate (L) was carried out to obtain a monometallic compound, [(Me4en)Pd(L)], in O,O{\textquoteright}-coordination mode. The bis(benzylthio)methylene group was bent strikingly from the palladium square plane at the dihedral angle of 70.40°. The physicochemical properties of the present palladium(II) compound were fully characterized by means of infrared and nuclear magnetic resonance spectroscopy, thermogravimetric analysis, and single-crystal X-ray diffraction measurement.",

keywords = "coordination mode, crystal engineering, NMR spectroscopy, X-ray diffraction",

author = "Noh, \{Tae Hwan\}",

year = "2023",

doi = "10.5806/AST.2023.36.4.198",

language = "English",

volume = "36",

pages = "198--203",

journal = "Analytical Science and Technology",

issn = "1225-0163",

number = "4",

}

TY - JOUR

T1 - Synthesis, crystal structure, and analytical characterizations of amphiphilic palladium(II) compound containing bis(benzylthio)methylenepropanedioate

AU - Noh, Tae Hwan

PY - 2023

Y1 - 2023

N2 - The reaction of cis-protected (Me4en)Pd(II) species with potentially multidentate bis(benzylthio)methy-lenepropanedioate (L) was carried out to obtain a monometallic compound, [(Me4en)Pd(L)], in O,O’-coordination mode. The bis(benzylthio)methylene group was bent strikingly from the palladium square plane at the dihedral angle of 70.40°. The physicochemical properties of the present palladium(II) compound were fully characterized by means of infrared and nuclear magnetic resonance spectroscopy, thermogravimetric analysis, and single-crystal X-ray diffraction measurement.

AB - The reaction of cis-protected (Me4en)Pd(II) species with potentially multidentate bis(benzylthio)methy-lenepropanedioate (L) was carried out to obtain a monometallic compound, [(Me4en)Pd(L)], in O,O’-coordination mode. The bis(benzylthio)methylene group was bent strikingly from the palladium square plane at the dihedral angle of 70.40°. The physicochemical properties of the present palladium(II) compound were fully characterized by means of infrared and nuclear magnetic resonance spectroscopy, thermogravimetric analysis, and single-crystal X-ray diffraction measurement.

KW - coordination mode

KW - crystal engineering

KW - NMR spectroscopy

KW - X-ray diffraction

UR - https://www.scopus.com/pages/publications/85170667792

U2 - 10.5806/AST.2023.36.4.198

DO - 10.5806/AST.2023.36.4.198

M3 - Journal article

AN - SCOPUS:85170667792

SN - 1225-0163

VL - 36

SP - 198

EP - 203

JO - Analytical Science and Technology

JF - Analytical Science and Technology

IS - 4

ER -

Synthesis, crystal structure, and analytical characterizations of amphiphilic palladium(II) compound containing bis(benzylthio)methylenepropanedioate

Abstract

Keywords

Quacquarelli Symonds(QS) Subject Topics

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