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Synthesis of zinc ferrite and its photocatalytic application under visible light

  • J. S. Jang
  • , S. J. Hong
  • , J. S. Lee
  • , Pramod H. Borse
  • , Ok Sang Jung
  • , T. E. Hong
  • , E. D. Jeong
  • , M. S. Won
  • , H. G. Kim*
  • *Corresponding author for this work
  • Pohang University of Science and Technology
  • International Advanced Research Centre for Powder Metallurgy and New Materials, Hyderabad
  • Pusan National University
  • Korea Basic Science Institute

Research output: Contribution to journalJournal articlepeer-review

Abstract

ZnFe2O4 with a spinel crystal structure was synthesized by using the solid-state reaction method. A single-phase ZnFe 2O4 was obtained in the temperature range of 900 - 1200 °C. The as-synthesized particles were agglomerates of crystals with an average size of 51.9 nm, as estimated from X-ray diffraction analysis. The band gap of the n-type semiconducting metal oxide, as determined by using UV-vis diffuse reflectance spectroscopy (UV-DRS) was found to be 1.90 eV (657 nm). The photocatalytic activity of ZnFe2O4 was investigated by using the photo-decomposition of isopropyl alcohol (IPA) under visible light (≥420 nm) and was found to be much higher than that of the well-known TiO2-xNx photocatalyst.

Original languageEnglish
Pages (from-to)204-208
Number of pages5
JournalJournal of the Korean Physical Society
Volume54
Issue number1
DOIs
StatePublished - 2009.01

Keywords

  • Calcium ferrites
  • Nano-particles
  • Photocatalytic activity
  • Polymerized complex method
  • Visible light

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