Tailor-made hexaethylene glycolic ionic liquids as organic catalysts for specific chemical reactions

Vinod H. Jadhav; Hwan Jeong Jeong; Seok Tae Lim; Myung Hee Sohn; Dong Wook Kim

doi:10.1021/ol200751e

Tailor-made hexaethylene glycolic ionic liquids as organic catalysts for specific chemical reactions

Vinod H. Jadhav
, Hwan Jeong Jeong
, Seok Tae Lim
, Myung Hee Sohn
, Dong Wook Kim

Department of Medicine

Jeonbuk National University

Research output: Contribution to journal › Journal article › peer-review

40 Scopus citations

Abstract

Chemical equations presented. Hexaethylene glycol substituted imidazolium based ionic liquids (hexaEGILs) were designed and prepared well-tailored to a specific organic reaction using alkali-metal fluorides (MFs) as multifunctional organic catalysts. These hexaEGIL catalysts could significantly enhance the reactivity of MF, even KF. Furthermore, the hexaEGIL systems showed tremendous efficiency in the nucleophilic fluorination of base-sensitive substrates.

Original language	English
Pages (from-to)	2502-2505
Number of pages	4
Journal	Organic Letters
Volume	13
Issue number	9
DOIs	https://doi.org/10.1021/ol200751e
State	Published - 2011.05.6

Quacquarelli Symonds(QS) Subject Topics

Engineering - Petroleum
Chemistry
Biological Sciences

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10.1021/ol200751e

Cite this

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title = "Tailor-made hexaethylene glycolic ionic liquids as organic catalysts for specific chemical reactions",

abstract = "Chemical equations presented. Hexaethylene glycol substituted imidazolium based ionic liquids (hexaEGILs) were designed and prepared well-tailored to a specific organic reaction using alkali-metal fluorides (MFs) as multifunctional organic catalysts. These hexaEGIL catalysts could significantly enhance the reactivity of MF, even KF. Furthermore, the hexaEGIL systems showed tremendous efficiency in the nucleophilic fluorination of base-sensitive substrates.",

author = "Jadhav, \{Vinod H.\} and Jeong, \{Hwan Jeong\} and Lim, \{Seok Tae\} and Sohn, \{Myung Hee\} and Kim, \{Dong Wook\}",

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doi = "10.1021/ol200751e",

language = "English",

volume = "13",

pages = "2502--2505",

journal = "Organic Letters",

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T1 - Tailor-made hexaethylene glycolic ionic liquids as organic catalysts for specific chemical reactions

AU - Jadhav, Vinod H.

AU - Jeong, Hwan Jeong

AU - Lim, Seok Tae

AU - Sohn, Myung Hee

AU - Kim, Dong Wook

PY - 2011/5/6

Y1 - 2011/5/6

N2 - Chemical equations presented. Hexaethylene glycol substituted imidazolium based ionic liquids (hexaEGILs) were designed and prepared well-tailored to a specific organic reaction using alkali-metal fluorides (MFs) as multifunctional organic catalysts. These hexaEGIL catalysts could significantly enhance the reactivity of MF, even KF. Furthermore, the hexaEGIL systems showed tremendous efficiency in the nucleophilic fluorination of base-sensitive substrates.

AB - Chemical equations presented. Hexaethylene glycol substituted imidazolium based ionic liquids (hexaEGILs) were designed and prepared well-tailored to a specific organic reaction using alkali-metal fluorides (MFs) as multifunctional organic catalysts. These hexaEGIL catalysts could significantly enhance the reactivity of MF, even KF. Furthermore, the hexaEGIL systems showed tremendous efficiency in the nucleophilic fluorination of base-sensitive substrates.

UR - https://www.scopus.com/pages/publications/79955580505

U2 - 10.1021/ol200751e

DO - 10.1021/ol200751e

M3 - Journal article

C2 - 21488659

AN - SCOPUS:79955580505

SN - 1523-7060

VL - 13

SP - 2502

EP - 2505

JO - Organic Letters

JF - Organic Letters

IS - 9

ER -

Tailor-made hexaethylene glycolic ionic liquids as organic catalysts for specific chemical reactions

Abstract

Quacquarelli Symonds(QS) Subject Topics

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