Thioether S-ligation in a side-on μ-η2:η2- peroxodicopper(ii) complex

Ga Young Park; Yunho Lee; Dong Heon Lee; Julia S. Woertink; A. A. Narducci Sarjeant; Edward I. Solomon; Kenneth D. Karlin

doi:10.1039/b918616f

Thioether S-ligation in a side-on μ-η²:η²- peroxodicopper(ii) complex

Ga Young Park
, Yunho Lee
, Dong Heon Lee
, Julia S. Woertink
, A. A. Narducci Sarjeant
, Edward I. Solomon
, Kenneth D. Karlin

Department of Chemistry

Johns Hopkins University
Stanford University
Ewha Womans University

Research output: Contribution to journal › Journal article › peer-review

29 Scopus citations

Abstract

[(ANS)Cu^I(CH₃CN)]⁺ reacts with O ₂ giving [{(ANS)Cu^II}₂(μ-η²: η²-O₂^2-)]²⁺, ν_O-O = 731 cm^-1, shown to possess S-thioether ligation, based on comparisons with analogues having all N-ligands or a -S(Ph) group. The finding is a rare occurrence and new for side-on O₂^2- binding.

Original language	English
Pages (from-to)	91-93
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	1
DOIs	https://doi.org/10.1039/b918616f
State	Published - 2010

Quacquarelli Symonds(QS) Subject Topics

Materials Science
Engineering - Petroleum
Engineering - Chemical
Chemistry

Access to Document

10.1039/b918616f

Cite this

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title = "Thioether S-ligation in a side-on μ-η2:η2- peroxodicopper(ii) complex",

abstract = "[(ANS)CuI(CH3CN)]+ reacts with O 2 giving [\{(ANS)CuII\}2(μ-η2: η2-O22-)]2+, νO-O = 731 cm-1, shown to possess S-thioether ligation, based on comparisons with analogues having all N-ligands or a -S(Ph) group. The finding is a rare occurrence and new for side-on O22- binding.",

author = "Park, \{Ga Young\} and Yunho Lee and Lee, \{Dong Heon\} and Woertink, \{Julia S.\} and \{Narducci Sarjeant\}, \{A. A.\} and Solomon, \{Edward I.\} and Karlin, \{Kenneth D.\}",

year = "2010",

doi = "10.1039/b918616f",

language = "English",

volume = "46",

pages = "91--93",

journal = "Chemical Communications",

issn = "1359-7345",

number = "1",

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TY - JOUR

T1 - Thioether S-ligation in a side-on μ-η2:η2- peroxodicopper(ii) complex

AU - Park, Ga Young

AU - Lee, Yunho

AU - Lee, Dong Heon

AU - Woertink, Julia S.

AU - Narducci Sarjeant, A. A.

AU - Solomon, Edward I.

AU - Karlin, Kenneth D.

PY - 2010

Y1 - 2010

N2 - [(ANS)CuI(CH3CN)]+ reacts with O 2 giving [{(ANS)CuII}2(μ-η2: η2-O22-)]2+, νO-O = 731 cm-1, shown to possess S-thioether ligation, based on comparisons with analogues having all N-ligands or a -S(Ph) group. The finding is a rare occurrence and new for side-on O22- binding.

AB - [(ANS)CuI(CH3CN)]+ reacts with O 2 giving [{(ANS)CuII}2(μ-η2: η2-O22-)]2+, νO-O = 731 cm-1, shown to possess S-thioether ligation, based on comparisons with analogues having all N-ligands or a -S(Ph) group. The finding is a rare occurrence and new for side-on O22- binding.

UR - https://www.scopus.com/pages/publications/72149113628

U2 - 10.1039/b918616f

DO - 10.1039/b918616f

M3 - Journal article

C2 - 20024303

AN - SCOPUS:72149113628

SN - 1359-7345

VL - 46

SP - 91

EP - 93

JO - Chemical Communications

JF - Chemical Communications

IS - 1