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Ultralarge and thermally stable electro-optic activities from supramolecular self-assembled molecular glasses

  • Tae Dong Kim
  • , Jae Wook Kang
  • , Jingdong Luo
  • , Sei Hum Jang
  • , Jae Won Ka
  • , Neil Tucker
  • , Jason B. Benedict
  • , Larry R. Dalton
  • , Tomoko Gray
  • , René M. Overney
  • , Dong Hun Park
  • , Warren N. Herman
  • , Alex K.Y. Jen*
  • *Corresponding author for this work
  • University of Washington
  • University of Maryland, College Park

Research output: Contribution to journalJournal articlepeer-review

Abstract

A series of molecular engineered organic glasses have been prepared to exploit the use of complementary Ar-ArF interactions to improve poling efficiency. These self-organized molecular glasses have also been used as host in the binary chromophore system to further improve the number density of chromophores and r33 values. Ultrahigh r33 values (up to 327 pm/V at the wavelength of 1310 nm) and good temporal stability could be achieved in these materials.

Original languageEnglish
Pages (from-to)488-489
Number of pages2
JournalJournal of the American Chemical Society
Volume129
Issue number3
DOIs
StatePublished - 2007.01.24

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