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Unified stress tensor of the hydration water layer

  • Bongsu Kim
  • , Qhwan Kim
  • , Soyoung Kwon
  • , Sangmin An
  • , Kunyoung Lee
  • , Manhee Lee
  • , Wonho Jhe*
  • *Corresponding author for this work
  • Seoul National University

Research output: Contribution to journalJournal articlepeer-review

Abstract

We present the general stress tensor of the ubiquitous hydration water layer (HWL), based on the empirical hydration force, by combining the elasticity and hydrodynamics theories. The tapping and shear component of the tensor describe the elastic and damping properties of the HWL, respectively, in good agreement with experiments. In particular, a unified understanding of HWL dynamics provides the otherwise unavailable intrinsic parameters of the HWL, which offer additional but unexplored aspects to the supercooled liquidity of the confined HWL. Our results may allow deeper insight on systems where the HWL is critical.

Original languageEnglish
Article number246102
JournalPhysical Review Letters
Volume111
Issue number24
DOIs
StatePublished - 2013.12.13

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