Unusual anion effects on the solution-behavior of cyclodimeric Pd(II) complex

Yoon Kyong Ryu; Cho Rong Kim; Tae Hwan Noh; Jae Kyun Lee; Ok Sang Jung

doi:10.1016/j.molstruc.2009.08.033

Unusual anion effects on the solution-behavior of cyclodimeric Pd(II) complex

Yoon Kyong Ryu
, Cho Rong Kim
, Tae Hwan Noh
, Jae Kyun Lee
, Ok Sang Jung^*

^*Corresponding author for this work

Chemistry Education

Pusan National University
Korea Institute of Science and Technology

Research output: Contribution to journal › Journal article › peer-review

2 Scopus citations

Abstract

Unusual anion effects on the solution-behavior of [(dppp)Pd(m-ptms)]₂(X)₄ (dppp = 1,3-bis(diphenylphosphino)propane; m-ptms = 1,3-bis(3-pyridyl)tetramethyldisiloxane; X^- = CF₃ SO₃^-, PF₆^-, ClO₄^-, and NO₃^-), based on the ¹H NMR chemical shifts and conductivity, were observed. The fluxionality of the cyclodimeric skeleton was found to be sensitive to the Hoffmeister series of anions.

Original language	English
Pages (from-to)	20-23
Number of pages	4
Journal	Journal of Molecular Structure
Volume	938
Issue number	1-3
DOIs	https://doi.org/10.1016/j.molstruc.2009.08.033
State	Published - 2009.12.16

Keywords

Anion effects
Anion exchange
Cyclodimer
Palladium(II) complex

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10.1016/j.molstruc.2009.08.033

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title = "Unusual anion effects on the solution-behavior of cyclodimeric Pd(II) complex",

abstract = "Unusual anion effects on the solution-behavior of [(dppp)Pd(m-ptms)]2(X)4 (dppp = 1,3-bis(diphenylphosphino)propane; m-ptms = 1,3-bis(3-pyridyl)tetramethyldisiloxane; X- = CF3 SO3-, PF6-, ClO4-, and NO3-), based on the 1H NMR chemical shifts and conductivity, were observed. The fluxionality of the cyclodimeric skeleton was found to be sensitive to the Hoffmeister series of anions.",

keywords = "Anion effects, Anion exchange, Cyclodimer, Palladium(II) complex",

author = "Ryu, \{Yoon Kyong\} and Kim, \{Cho Rong\} and Noh, \{Tae Hwan\} and Lee, \{Jae Kyun\} and Jung, \{Ok Sang\}",

year = "2009",

month = dec,

day = "16",

doi = "10.1016/j.molstruc.2009.08.033",

language = "English",

volume = "938",

pages = "20--23",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

number = "1-3",

}

TY - JOUR

T1 - Unusual anion effects on the solution-behavior of cyclodimeric Pd(II) complex

AU - Ryu, Yoon Kyong

AU - Kim, Cho Rong

AU - Noh, Tae Hwan

AU - Lee, Jae Kyun

AU - Jung, Ok Sang

PY - 2009/12/16

Y1 - 2009/12/16

N2 - Unusual anion effects on the solution-behavior of [(dppp)Pd(m-ptms)]2(X)4 (dppp = 1,3-bis(diphenylphosphino)propane; m-ptms = 1,3-bis(3-pyridyl)tetramethyldisiloxane; X- = CF3 SO3-, PF6-, ClO4-, and NO3-), based on the 1H NMR chemical shifts and conductivity, were observed. The fluxionality of the cyclodimeric skeleton was found to be sensitive to the Hoffmeister series of anions.

AB - Unusual anion effects on the solution-behavior of [(dppp)Pd(m-ptms)]2(X)4 (dppp = 1,3-bis(diphenylphosphino)propane; m-ptms = 1,3-bis(3-pyridyl)tetramethyldisiloxane; X- = CF3 SO3-, PF6-, ClO4-, and NO3-), based on the 1H NMR chemical shifts and conductivity, were observed. The fluxionality of the cyclodimeric skeleton was found to be sensitive to the Hoffmeister series of anions.

KW - Anion effects

KW - Anion exchange

KW - Cyclodimer

KW - Palladium(II) complex

UR - https://www.scopus.com/pages/publications/70449642425

U2 - 10.1016/j.molstruc.2009.08.033

DO - 10.1016/j.molstruc.2009.08.033

M3 - Journal article

AN - SCOPUS:70449642425

SN - 0022-2860

VL - 938

SP - 20

EP - 23

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

IS - 1-3

ER -

Unusual anion effects on the solution-behavior of cyclodimeric Pd(II) complex

Abstract

Keywords

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