Unusual fluorenylidene-philic interactions for effective conformational induction

Young A. Lee; Ok Sang Jung

doi:10.1002/1521-3773(20011015)40:20<3868::AID-ANIE3868>3.0.CO;2-O

Unusual fluorenylidene-philic interactions for effective conformational induction

Young A. Lee
, Ok Sang Jung^*

^*Corresponding author for this work

Department of Chemistry

Korea Institute of Science and Technology

Research output: Contribution to journal › Journal article › peer-review

26 Scopus citations

Abstract

Control of the conformation of the fluorenylidene moiety is achieved through an intramolecular interaction between the fluorenylidene moiety and the axial ligand during the oxidative addition and successive substitution of [Pt^II(fm)] to give Pt^IV(X)(X′)(fm)] (fm = 9-fluorenylidenemalonate; see scheme). The conformation of the fm moiety can be effectively induced by the fluorenylidene-philicity of the axial X/X′ ligands, OOCCH₃ > OCH₃ > OH.

Original language	English
Pages (from-to)	3868-3870
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	40
Issue number	20
DOIs	https://doi.org/10.1002/1521-3773(20011015)40:20<3868::AID-ANIE3868>3.0.CO;2-O
State	Published - 2001.10.15

Keywords

Arene ligands
Conformation analysis
Noncovalent interactions
Oxidative addition
Platinum

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10.1002/1521-3773(20011015)40:20<3868::AID-ANIE3868>3.0.CO;2-O

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title = "Unusual fluorenylidene-philic interactions for effective conformational induction",

abstract = "Control of the conformation of the fluorenylidene moiety is achieved through an intramolecular interaction between the fluorenylidene moiety and the axial ligand during the oxidative addition and successive substitution of [PtII(fm)] to give PtIV(X)(X′)(fm)] (fm = 9-fluorenylidenemalonate; see scheme). The conformation of the fm moiety can be effectively induced by the fluorenylidene-philicity of the axial X/X′ ligands, OOCCH3 > OCH3 > OH.",

keywords = "Arene ligands, Conformation analysis, Noncovalent interactions, Oxidative addition, Platinum",

author = "Lee, \{Young A.\} and Jung, \{Ok Sang\}",

year = "2001",

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doi = "10.1002/1521-3773(20011015)40:20<3868::AID-ANIE3868>3.0.CO;2-O",

language = "English",

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journal = "Angewandte Chemie - International Edition",

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TY - JOUR

T1 - Unusual fluorenylidene-philic interactions for effective conformational induction

AU - Lee, Young A.

AU - Jung, Ok Sang

PY - 2001/10/15

Y1 - 2001/10/15

N2 - Control of the conformation of the fluorenylidene moiety is achieved through an intramolecular interaction between the fluorenylidene moiety and the axial ligand during the oxidative addition and successive substitution of [PtII(fm)] to give PtIV(X)(X′)(fm)] (fm = 9-fluorenylidenemalonate; see scheme). The conformation of the fm moiety can be effectively induced by the fluorenylidene-philicity of the axial X/X′ ligands, OOCCH3 > OCH3 > OH.

AB - Control of the conformation of the fluorenylidene moiety is achieved through an intramolecular interaction between the fluorenylidene moiety and the axial ligand during the oxidative addition and successive substitution of [PtII(fm)] to give PtIV(X)(X′)(fm)] (fm = 9-fluorenylidenemalonate; see scheme). The conformation of the fm moiety can be effectively induced by the fluorenylidene-philicity of the axial X/X′ ligands, OOCCH3 > OCH3 > OH.

KW - Arene ligands

KW - Conformation analysis

KW - Noncovalent interactions

KW - Oxidative addition

KW - Platinum

UR - https://www.scopus.com/pages/publications/0035886850

U2 - 10.1002/1521-3773(20011015)40:20<3868::AID-ANIE3868>3.0.CO;2-O

DO - 10.1002/1521-3773(20011015)40:20<3868::AID-ANIE3868>3.0.CO;2-O

M3 - Journal article

AN - SCOPUS:0035886850

SN - 1433-7851

VL - 40

SP - 3868

EP - 3870

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 20

ER -

Unusual fluorenylidene-philic interactions for effective conformational induction

Abstract

Keywords

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