Water splitting on Rhodamine-B dye sensitized Co-doped TiO 2 catalyst under visible light

Research output: Contribution to journalJournal articlepeer-review

Abstract

An effective rhodamine B (Rh B) dye sensitized Co doped TiO 2 (Co/TiO 2) materials was prepared by simple physical absorption for photocatalytic water splitting under visible light. The prepared Rh B-Co/TiO 2 materials showed a strong absorbance edge band in the range of 450-600nm (max. absorbance at 550nm) and estimated a moderate band gap of 2.58eV, which lowered than that of Co/TiO 2 (2.75eV). Rh B-Co/TiO 2 catalysts showed the high activity towards photocatalytic water splitting under visible light irradiation. The reaction with Rh B-Co/TiO 2 catalysts achieved a nearly stoichiometic evolution of H 2 and O 2 evolution of ∼227.3μmol/g-catal/h and ∼98.9μmol/g-catal/h, respectively, which is 6 times higher than that of H 2 evolution (∼37.67μmol/g-catal/h) over Co/TiO 2 catalysts. The enhanced water splitting reaction may be facilitated by the absorbed Rh B near to Co atom. This synergic effect between the Rh B and Co is crucial to the water splitting reaction.

Original languageEnglish
Pages (from-to)397-401
Number of pages5
JournalApplied Catalysis B: Environmental
Volume111-112
DOIs
StatePublished - 2012.01.12

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

  1. SDG 7 - Affordable and Clean Energy
    SDG 7 Affordable and Clean Energy

Keywords

  • Dye sensitization
  • Photocatalyst
  • Rhodamine B dye
  • TiO nanoparticles
  • Water splitting

Quacquarelli Symonds(QS) Subject Topics

  • Environmental Sciences
  • Engineering - Petroleum
  • Engineering - Chemical

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